Optically Active Tetrapyrazinoporphyrazines and Their Circular Dichroism in Monomeric and Dimeric FormsOxford University Press (OUP) - Tập 27 Số 8 - Trang 851-852 - 1998
Nagao Kobayashi, W. A. Nevin
Abstract Metal-free and copper derivatives of tetrapyrazinoporphyrazines
containing four (1R)-(−)- or (1S)-(+)-camphor units have been synthesized and
their circular dichroism (CD) has been studied: in monomeric state, R and S
isomers showed mainly positive and negative CD signs, respectively, while CD
pattern in a cofacial dimeric state suggested that R and S isomers stack in
left- and right-hand... hiện toàn bộ
Fluoranthocyanine: A New Member of the Phthalocyanine FamilyOxford University Press (OUP) - Tập 27 Số 5 - Trang 423-424 - 1998
Nagao Kobayashi, Yuko Yoshikawa, Osamu Ito, H. Bruce Goodbrand, Jim Mayo
Abstract Fluoranthocyanine, a phthalocyanine analog fused by four five-membered
rings and four 1,8-naphthalene units, has been synthesized and characterized by
electronic absorption, magnetic circular dichroism, and fluorescence
spectroscopy.
Isolation and Structure of Magnoloside A, a New Phenylpropanoid Glycoside from Magnolia obovata Thunb.Oxford University Press (OUP) - Tập 17 Số 1 - Trang 163-166 - 1988
Takashi Hasegawa, Yoshiyasu Fukuyama, Toshihide Yamada, Kazuyuki Nakagawa
Abstract Magnoloside A, a novel phenylpropanoid glycoside has been isolated from
the MeOH extract of Magnolia obovata and its structure has been elucidated as
3,4-dihydroxy-β-phenyl-ethyl-O-α-l-rhamnopyranosyl-(1→2)-3-O-caffeoyl-β-d-allopyranoside
by means of spectroscopic and chemical evidences.
Enantioselective Syntheses of (+)- and (−)-FrontalinOxford University Press (OUP) - Tập 16 Số 1 - Trang 41-44 - 1987
Masaki Ohwa, Ernest L. Eliel
Abstract (+)- and (−)-Frontalin have been obtained from a chiral 1,3-oxathiane
precursor in a short (3-step) synthesis in moderate (70%) enantiomeric excess
(e.e.). A longer (6-step) modification gives the two enantiomers in 96% e.e.
Overall yields range from 28 to 43%.
1H NMR Study of Hydroxy Groups in Mesoporous Molecular Sieve SBA-15Oxford University Press (OUP) - Tập 30 Số 11 - Trang 1164-1165 - 2001
Lei Shi, Yan Zou, Heyong He
Abstract Three types of hydroxy groups, which are attributed to single,
hydrogen-bonded and geminal SiOHs in mesoporous molecular sieve SBA-15 are
directly and quantitatively observed by 1H ultrafast MAS NMR spectroscopy.
A New Ternary Compound in Rare Earth-Cobalt-Boron SystemOxford University Press (OUP) - Tập 1 Số 10 - Trang 875-876 - 1972
Koichi Niihara, Seishi Yajima
Abstract A new ternary boride RCo12B6 with a rhombohedral structure was
synthesized by arc-melting in R-Co-B system, where R is a rare earth ion. From
magnetic measurements, it was found that CeCo12B6 had a Curie temperature at
130°–140°K and exhibited a Curie–Weiss behavior in the paramagnetic region above
140°K.
Selective Electrochemical Response of Dopamine against 3,4-Dihydroxyphenylacetic Acid at Bare Indium–Tin Oxide ElectrodeOxford University Press (OUP) - Tập 34 Số 8 - Trang 1120-1121 - 2005
Guobao Xu, Osamu Niwa, Osamu Niwa
Abstract Electrochemistry of dopamine and 3,4-dihydroxyphenylacetic acid at ITO
were investigated. The oxidation of dopamine significantly depended on pH and
supporting electrolyte. The peak current increased more than one hundred folds
with increasing pH from 2.5 to 10.0 in phosphate buffer. Moreover, selective
oxidation of dopamine against 3,4-dihydroxyphenylacetic acid at bare ITO was
observed.... hiện toàn bộ