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The Effect of Polymer Structures on Complete Degradation: A First‐Principles Study
ChemistryOpen - Tập 7 Số 6 - Trang 463-466 - 2018
Yu Zhu, Depeng Zhang, Zhanwen Zhang, Zhigang Wang
AbstractThe widespread application of hydrocarbon polymer materials has spurred an increasing interest in the study of their dissociation mechanism, which is related to key issues such as environmental protection. In this work, the last‐step dissociation characteristics of carbon chain polymers were investigated. By using density functional theory, we considered all possible structures, including ... hiện toàn bộ
Voltammetric Study of the Influence of Various Phosphate Anions on Silver Nanoparticle Oxidation
ChemistryOpen - Tập 4 Số 5 - Trang 595-599 - 2015
D. V. Navolotskaya, Her Shuang Toh, Christopher Batchelor‐McAuley, Richard G. Compton
AbstractThe antibacterial properties of silver are strongly controlled by the redox couple of silver/silver(I). This work reports the influence of phosphate anions on silver nanoparticle oxidation, which is important given the abundance of phosphate species in biological systems. The three different species of anions were found to have a varying degree of influence on silver oxidation with the ord... hiện toàn bộ
CO2 Cycloaddition to Epoxides by using M‐DABCO Metal–Organic Frameworks and the Influence of the Synthetic Method on Catalytic Reactivity
ChemistryOpen - Tập 6 Số 5 - Trang 674-680 - 2017
Bibimaryam Mousavi, Somboon Chaemchuen, Behrooz Moosavi, Kui Zhou, Mekhman S. Yusubov, Francis Verpoort
AbstractA series of high‐quality M2(BDC)2(DABCO) metal–organic frameworks (abbreviated as M‐DABCO; M=Zn, Co, Ni, Cu; BDC=1,4‐benzene dicarboxylate; DABCO=1,4‐diazabicyclo[2.2.2]octane), were synthesized by using a solvothermal (SV) method, and their catalytic activity for the cycloaddition of CO2 to epoxides in the absence of a co‐catalyst or solvent was demonstrated. Of these metal–organic framew... hiện toàn bộ
Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium Salts
ChemistryOpen - Tập 1 Số 3 - Trang 130-133 - 2012
Peter Schroll, Durga Prasad Hari, Burkhard König
Functional Systems Derived from Nucleobase Self‐assembly
ChemistryOpen - Tập 9 Số 4 - Trang 409-430 - 2020
Anselmo del Prado, David González‐Rodríguez, Yi‐Lin Wu
AbstractDynamic and reversible non‐covalent interactions endow synthetic systems and materials with smart adaptive functions that allow them to response to diverse stimuli, interact with external agents, or repair structural defects. Inspired by the outstanding performance and selectivity of DNA in living systems, scientists are increasingly employing Watson−Crick nucleobase pairing to control the... hiện toàn bộ
A Multi‐target Small Molecule for Targeted Transcriptional Activation of Therapeutically Significant Nervous System Genes
ChemistryOpen - Tập 5 Số 6 - Trang 517-521 - 2016
Yulei Wei, Ganesh N. Pandian, Tingting Zou, Junichi Taniguchi, Shinsuke Sato, Gengo Kashiwazaki, Thangavel Vaijayanthi, T. Hidaka, Toshikazu Bando, Hiroshi Sugiyama
AbstractAn integrated multi‐target small molecule capable of altering dynamic epigenetic and transcription programs associated with the brain and nervous system has versatile applications in the regulation of therapeutic and cell‐fate genes. Recently, we have been constructing targeted epigenetic ON switches by integrating sequence‐specific DNA binding pyrrole‐imidazole polyamides with a potent hi... hiện toàn bộ
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