p-Type Characteristics of Cu-Doped CdS Thin Films

Japanese Journal of Applied Physics - Tập 31 Số 4R - Trang 1170 - 1992
Yasube Kashiwaba1, Itaru Kanno Itaru Kanno1, Toshio Ikeda Toshio Ikeda1
1Department of Electronic Engineering, Faculty of Engineering, Iwate University, Morioka 020

Tóm tắt

The characteristics of Cu-doped CdS films have been studied. Cu was easily diffused into CdS films when CdS was deposited on a Cu film successively at 200°C. The resistivity of the films increased initially with increasing Cu doping, but decreased for values of the Cu/Cd atomic ratio over about 0.5%. The Seebeck coefficient changed from negative to positive, and the Hall coefficient also changed from negative to positive with increasing Cu doping. I-V characteristics of a cell with a CdS(Cu-doped)/CdS(non-doped) film structure showed rectification. Thus, Cu-doped CdS films show p-type characteristics. It is proposed that the Cu compensates the donor due to S-vacancies, and the conductivity type of the CdS films was converted to p-type.

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Tài liệu tham khảo

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