Water‐ethanol separation by pervaporation through plasma graft polymerized membranes

Wiley - Tập 34 Số 3 - Trang 1159-1172 - 1987
Toshihiro Hirotsu1
1Research Institute for Polymers and Textiles, 1‐1‐4 Yatabe‐Higashi, Tsukuba, Ibaraki 305, Japan

Tóm tắt

AbstractWater‐ethanol permselective membranes were prepared through plasma graft polymerization of acrylic acid, methacrylic acid, and acrylamide onto porous polypropylene film. In these membranes, the functions of permseparation and mechanical properties are shared respectively to the graft polymer layer and the substrate film. Higher permselectivity of water is achieved with the ionization of the acrylic acid and the methacrylic acid‐grafted membranes. Permselectivity is dependent on the degree of grafting, and it is necessary to fill the pores of substrate film with graft polymers. Permseparation of water was investigated with respect to the feed ethanol concentration and also to the temperature dependence.

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