Unexpectedly High Minority‐Carrier Lifetimes Exceeding 20 ms Measured on 1.4‐Ω cm n‐Type Silicon Wafers

Boris Veith‐Wolf1, Jan Schmidt2,1
1Institute for Solar Energy Research Hamelin (ISFH), Am Ohrberg 1, 31860 Emmerthal, Germany
2Department of Solar Energy, Institute of Solid‐State Physics, Leibniz Universität Hannover Appelstrasse 2 30167 Hannover Germany

Tóm tắt

We measure very high minority‐carrier lifetimes exceeding 20 ms on 1.4‐Ω cm n‐type Czochralski silicon wafers passivated using plasma‐assisted atomic‐layer‐deposited Al2O3 on both wafer surfaces. The measured maximum effective lifetimes are surprisingly high as they significantly exceed the intrinsic lifetime limit previously reported in the literature. We are able to measure such high lifetimes by realizing an exceptionally homogeneous Al2O3 surface passivation on large‐area samples (12.5 × 12.5 cm2). The importance of the homogeneous passivation is demonstrated by comparison with samples of locally reduced passivation quality.

Từ khóa


Tài liệu tham khảo

10.1016/j.solmat.2006.04.014

10.1063/1.2240736

10.1063/1.2963707

10.1002/pssr.200903209

10.1063/1.3587227

10.1063/1.3250157

10.1016/j.egypro.2012.07.080

10.1002/pssr.200903140

J.Schmidt F.Werner B.Veith D.Zielke R.Bock V.Tiba P.Poodt F.Roozeboom A.Li A.Cuevas R.Brendel in Proceedings of the 25th European Photovoltaic Solar Energy Conference Valencia Spain 2010(WIP Munich Germany 2010) pp.1130–1133.

10.1103/PhysRevB.86.165202

10.1063/1.3700241

S.Steingrube P. P.Altermatt D.Zielke F.Werner J.Schmidt R.Brendel in Proceedings of the 25th European Photovoltaic Solar Energy Conference Valencia Spain 2010(WIP Munich Germany 2010) pp.1748–1754.

10.1016/j.solmat.2013.06.049

10.1149/1.2086825

10.1002/pssr.200802192

Y.Wan K. R.McIntosh A. F.Thomson A.Cuevas in Proceedings of the 38th IEEE Photovoltaic Specialists Conference Austin TX USA 2012 Part 2 (IEEE New York USA 2012) pp.1–7.

10.1109/JPHOTOV.2017.2713411

10.1063/1.1432476

10.1063/1.1610231

10.1063/1.89694