Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
Tóm tắt
Từ khóa
Tài liệu tham khảo
Strikjers G. J., Dalderop J. H. J., Broeksteeg M. A. A., Swagten J. J. M., de Jonge W. J. M., J. Appl. Phys. 86, 5141 (1999).
S. Kawai Symposium on Electrochemical Technology in Electronics (Electrochemical Society Pennington NJ 1987).
The room-temperature electrolyte bath contained 20% by volume methanol Co salt (1.3 M CoSO 4 ·5H 2 O) and a buffering acid (0.7 M H 3 BO 3 ) at a pH of 3.7 prefiltered through a 0.2-μm filter. A standard three-electrode cell configuration (38) was used with a computer-controlled galvanostatic (constant current) electroplating circuit. The exposed gold on the template sample forms the working electrode and its half-cell potential is monitored with respect to a standard calomel reference electrode (SCE). The counterelectrode is a platinum foil with an 8-cm 2 surface area. A potential at least as negative as −0.52 V (the half-cell electrode potential against the SCE for Co 2+ + 2e − → Co) must be applied by the biasing circuit. Electrodeposition begins at the exposed gold at the base of each nanopore and grows upward as the pore is filled. Electrodeposition ensures continuity of the nanowire wires because otherwise growth cannot be sustained. Constant-current densities of 30 to 300 A/m 2 resulted in deposition rates of 1 to 10 nm/s. We controlled nanowire height by monitoring the integrated current.
SAXS experiments were performed with Ni-filtered Cu-Kα radiation from a Rigaku rotating anode operated at 8 kW with pinhole collimation at an angle of incidence of 45°. The scattering was recorded on a gas-filled area detector (Siemens Hi-Star). The electron densities (in e − /Å 3 ) are given in parentheses for PS (0.341) PMMA (0.386) water (0.335) water-methanol (0.319) and Co (2.456).
See for example the discussion of LIGA in M. Madou Fundamentals of Microfabrication (CRC Press Boca Raton FL 1997).
Sun L., Searson D. C., Chien C. L., J. Appl. Phys. 74, 2803 (1999).
A. J. Bard L. R. Faulkner Electrochemical Methods (Wiley New York 1980).
We are grateful to A. Fadeev for helpful discussions concerning the choice of a suitable surfactant and C. Stafford for the preparation of the block copolymer. T.T.-A. acknowledges support by the Deutsche Forschungsgemeinschaft. Funded by the National Science Foundation “Partnership in Nanotechnology” grant the Materials Research Science and Engineering Center and the U.S. Department of Energy.