The two-wavelength laser cleaning methodology; theoretical background and examples from its application on CH objects and monuments with emphasis to the Athens Acropolis sculptures

Springer Science and Business Media LLC - Tập 4 - Trang 1-11 - 2016
Paraskevi Pouli1, Evi Papakonstantinou2, Katerina Frantzikinaki2, Anastasia Panou2, Giasemi Frantzi2, Costantinos Vasiliadis3, Costas Fotakis1
1Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, (IESL-FORTH), Heraklion, Greece
2Acropolis Restoration Service, Athens, Greece
3Acropolis Museum, Athens, Greece

Tóm tắt

The two-wavelength laser cleaning methodology has been introduced and developed in order to meet demanding cleaning challenges in CH. The innovation lies on the combined use of two laser beams, allowing thus control of the laser ablation effective regimes towards an efficient and safe cleaning result. A series of studies on technical samples and real fragments aimed at defining and refining this methodology in order to ensure that the original surface, including its details and historic traces, will be safeguarded. In this paper related research and applications will be presented in an attempt to enlighten the associated laser ablation processes, as well as the potential cleaning applications in CH field. Laser-assisted removal of pollution accumulations from the Athens Acropolis monuments and sculptures is a unique highlight on the use of this methodology in practice. IESL-FORTH in collaboration with the Acropolis Restoration Service and the Acropolis Museum has developed an innovative cleaning methodology and a prototype laser cleaning system, which since 2002 have been introduced to the everyday conservation practice and will be presented in this paper.

Tài liệu tham khảo

Fotakis C, Anglos D, Zafiropulos V, Georgiou S, Tornari V. Lasers in the preservation of cultural heritage. Principles and applications. New York: Taylor and Francis; 2006. Cooper MI. Laser cleaning in conservation: an introduction. Oxford: Butterworth-Heinemann; 1998. Vergès-Belmin V, Dignard C. Laser yellowing myth or reality. Journal of Cultural Heritage. 2003;4(Suppl):238s–44s. Zafiropulos V, Balas C, Manousaki A, Marakis Y, Maravelaki-Kalaitzaki P, Melesanaki K, Pouli P, Stratoudaki T, Klein S, Hildenhagen J, Dickmann K, LukYanchuk BS, Mujat C, Dogariu A. Yellowing effect and discoloration of pigments: experimental and theoretical studies. J Cult HeriT. 2003;4:249–56. Klein S, Ferksanati F, Hildenhagen J, Dickmann K, Uphoff H, Marakis Y, Zafiropulos V. Discoloration of marble during laser cleaning by Nd:YAG laser wavelengths. Appl Surf Sci. 2001;171:242–51. Dickmann K, Klein S, Zafiropulos V. Laser cleaning of marble: discoloration effects using various Nd:YAG laser wavelengths (ω, 2ω, 3ω). In: Salimbeni R, editor. Laser techniques and systems in art conservation, vol. 4402. Washington: SPIE—The International Society for Optical Engineering; 2001. p. 54–67. Gavino M, Hermosin B, Castillejo M, Oujja M, Rebollar E, Vergès-Belmin V, Nowik W, Saiz-Jimenez C. Black crusts removal: the effect of stone yellowing and cleaning strategies. In: Saiz-Jimenez C, editor. Air Pollution and cultural heritage. London: AA Balkema; 2004. p. 239–45. Gracia M, Gaviño M, Vergès-Belmin V, Hermosin B. Mössbauer and XRD study of the effect of Nd:YAG-1064 nm laser irradiation on hematite present in model samples. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V). Springer proceedings in physics 100. Heidelberg: Springer; 2005. p. 341–6. Potgieter-Vermaak SS, Godoi RHM, van Grieken R, Potgieter JH, Oujja M, Castillejo M. Micro-structural characterization of black crust and laser cleaning of building stones by micro-Raman and SEM techniques. Spectrochim Acta A. 2005;61:2460–7. Zafiropulos V, Pouli P, Kylikoglou V, MaravelakiKalaitzaki P, Lukyanchuk BS, Dogariu A. Synchronous use of IR and UV laser pulses in the removal of encrustation: mechanistic aspects, discoloration phenomena and benefits. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V) Springer Proceedings in Physics 100. Heidelberg: Springer; 2005. p. 311–8. Zhang J, Birnbaum AJ, Yao YL, Xu F, Lombardi JR. Effect of fluence on the discoloration of marble cleaned with UV lasers. Appl Surf Sci. 2007;253:3083–91. Pouli P, Emmony DC, Madden CE, Sutherland I. Analysis of the laser-induced reduction mechanisms of medieval pigments. Appl Surf Sci. 2001;173:252–61. Castillejo M, Martin M, Oujja M, Silva D, Torres R, Manousaki A, Zafiropulos V, Van den Brink OF, Heeren RMA, Teule R, Silva A, Gouveia H. Analytical study of the chemical and physical changes induced by KrF laser cleaning of tempera paints. Anal Chem. 2002;74:4662–71. Cooper MI, Fowles PS, Tang CC. Analysis of the laser-induced discoloration of lead white pigment. App. Surf. Sci. 2002;201:75–84. Hildenhagen J, Chappé M, Dickmann K. Reaction of historical colours and their components irradiated at different Nd:YAG laser wavelengths (ω, 2ω, 3ω, 4ω). In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V). Springer Proceedings in Physics 100. Heidelberg: Springer; 2005. p. 297–302. Oujja M, Sanz M, Rebollar E, Marco JF, Castillejo M, Pouli P, Kogou S, Fotakis C. Wavelength and pulse duration effects on laser induced changes on raw pigments used in paintings. Spectrochim. Acta A. 2013;102:7–14. Siano S, Margheri F, Pini R, Mazzinghi P, Salimbeni R. Cleaning processes of encrusted marbles by Nd:YAG lasers operating in free-running and Q-switching regimes. Appl Opt. 1997;36:7073–9. Pouli P, Oujja M, Castillejo M. Practical issues in laser cleaning of stone and painted artefacts: optimization procedures and side effects. Appl Phys A. 2012;106:447–64. de Oliveira C, Vergès-Belmin V, Demaille D, Bromblet P. Lamp black and hematite contribution to laser yellowing: A study on technical gypsum samples. Stud Conserv. 2015. doi:10.1179/2047058415Y.0000000003. Papanikolaou A. Towards the understanding of the double wavelength laser cleaning in avoiding laser yellowing on stonework. PhD Thesis. University of Crete, Department of Physics, 2015. Marakis G, Pouli P, Zafiropulos V, Maravelaki-Kalaitzaki P. Comparative study on the application of the first and the third harmonic of a Nd:YAG laser system to clean black encrustation on marble. J Cult Herit. 2003;4:S83–91. Bartoli L, Pouli P, Fotakis C, Siano S, Salimbeni R. Characterization of stone cleaning by Nd:YAG lasers with different pulse duration. Laser Chemistry. 2006;81750. de Cruz A, Wolbarsht ML, Palmer RA, Pierce SE, Adamkiewicz E. Er:YAG laser applications on marble and limestone sculptures with polychrome and patina surfaces. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V) Springer Proceedings in Physics 100. Heidelberg: Springer; 2005. p. 113–24. Siano S, Giamello M, Bartoli L, Mencaglia A, Parfenov V, Salimbeni R. Laser cleaning of stone by different laser pulse duration and wavelength. Laser Phys. 2008;18:27–36. Asmus JF, Seracini M, Zetler MJ. Surface morphology of laser-cleaned stone. Lithoclastia. 1976;1:23–46. Beadman K, Scarrow J. Laser cleaning Lincoln Cathedral’s Romanesque Frieze. Journal of Architectural Conservation. 1998;4:39–53. Armani E, Calcagno G, Menichelli C, Rossetti M. The church of the Maddalena in Venice: the use of laser in the cleaning of the façade. Journal of Cultural Heritage. 2000;1(Suppl):S99–104. Calcagno G, Pummer E, Koller M. St. Stephen’s church in Vienna: criteria for Nd:YAG laser cleaning on an architectural scale. J Cult Herit. 2000;1(Suppl):S111–7. Siano S, Giusti A, Pinna D, Porcinai S, Giamello M, Sabatini G, Salimbeni R. The conservation intervention on the Porta della Mandorla. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V). Springer Proceedings in Physics 100. Heiderberg: Springer; 2005. p. 171–8. Pouli P, Fotakis C, Hermosin B, Saiz-Jimenez C, Domingo C, Oujja M, Castillejo M. The laser-induced discoloration of stonework; a comparative study on its origins and remedies. Spectrochim Acta A. 2008;71:932–45. Pouli P, Zafiropulos V, Fotakis C. The combination of ultraviolet and infrared laser radiation for the removal of unwanted encrustation from stonework; a novel laser cleaning methodology. In: Kwiatkowski D, Lofvendahl RR, editors. The Proceedings of the 10th International Congress on Deterioration and Conservation of Stone ICOMOS, Stockholm Sweden. Sweden: ICOMOS; 2004. p. 801–8. Pouli P, Frantzikinaki K, Papakonstantinou E, Zafiropulos V, Fotakis C. Pollution encrustation removal by means of combined ultraviolet and infrared laser radiation: The application of this innovative methodology on the surface of the Parthenon west Frieze. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V), Springer Proceedings in Physics 100. Heidelberg: Springer; 2005. p. 333–40. Frantzikinaki K, Marakis G, Panou A, Vasiliadis C, Papakonstantinou E, Pouli P, Ditsa Th, Zafiropulos V, Fotakis C. The cleaning of the Parthenon West Frieze by means of combined infrared and ultraviolet radiation. In: Nimmrichter J, Kautek W, Schreiner M, editors. The Proceedings of the 6th International Conference on Lasers in the Conservation of Artworks (LACONA VI) Springer Proceedings in Physics 116. Heidelberg: Springer; 2007. p. 97–104. Maravelaki-Kalaitzaki P. Black crusts and patinas on Pentelic marble from the Parthenon and Erechtheum (Acropolis, Athens): characterization and origin. Anal Chim Acta. 2005;532:187–98. Skoulikidis T, Charalambous D, Papakonstantinou E, Beloyannis N. The mechanism of marble sulfation by SO2 action. In: The Proceedings of the 3rd International Congress on Deterioration and Preservation of Stones, Venice. Padua: Univ degli Studi di Padova; 1979. p. 439–452. Skoulikidis T. Proposal for the cleaning of the Acropolis monuments. In study for the restoration of the Parthenon, vol. 3c. Athens: Greek Ministry of Culture: The Acropolis Restoration Service; 1994 (in Greek with English summaries). Galanos A, Doganis Y. The remnants of the epidermis on the Parthenon; a valuable analytical tool for assessing condition. Stud Conserv. 2003;48:3–16. Tanguy E, Huet N, Vinçotte A. Lasers cleaning of patrimonial plasters. In: Dickmann K, Fotakis C, Asmus JF, editors. The Proceedings of the 5th International Conference on Lasers in the Conservation of Artworks (LACONA V) Springer Proceedings in Physics 100. Heidelberg: Springer; 2005. p. 125–32. Grammatikakis G, Demadis KD, Melessanaki K, Pouli P. Laser-assisted removal of dark cement crusts from mineral gypsum (selenite) architectural elements of peripheral monuments at Knossos. Stud Conserv. 2015;60(Suppl 1):S3–11.