The petrological characteristics and significance of organic-rich shale in the Chang 7 member of the Yanchang Formation, south margin of the Ordos basin, central China

Elsevier BV - Tập 16 Số 6 - Trang 1255-1269 - 2019
Sen Li1, Rixiang Zhu1, Jingwei Cui1, Zhendong Luo1, Jinggang Cui1, Han Liu1, Weiqiang Li1
1Research Institute of Petroleum Exploration and Development, Beijing 100083, China

Tóm tắt

AbstractThe organic-rich shale of the Chang 7 member is the most important source rock in the Ordos basin. The sedimentary environment and the controlling factors of organic matter enrichment, however, are still in contention. In this investigation, the Yishicun outcrop, located on the south margin of the Ordos basin, has been considered for the study. X-ray diffraction, polarizing microscopy, field emission scanning electron microscopy and cathodoluminescence (CL) were used to investigate the petrological features of the organic-rich shale. The content of volcanic ash and the diameter of pyrite framboid pseudocrystals were measured to illustrate the relationship between oxygen level, ash content and the enrichment of organic matter. It has been found that the diameter of pyrite framboid pseudocrystals has a strong correlation with the total organic carbon, demonstrating that the redox status degree of the water column has a positive impact on the enrichment of organic matter. Additionally, with an increase in the ash content, the content of organic matter increased at first and then decreased, and reached a maximum when the ash content was about 6%, illustrating that the ash input has a double effect on the enrichment of organic matter.

Từ khóa


Tài liệu tham khảo

Betts JN, Holland HD. The oxygen content of ocean bottom waters, the burial efficiency of organic carbon, and the regulation of atmospheric oxygen. Glob Planet Change. 1991;97(5):5–18. https://doi.org/10.1016/0921-8181(91)90123-E.

Cui JW, Zhu RK, Luo Z, et al. Sedimentary and geochemical characteristics of the Triassic Chang 7 member shale in the southeastern Ordos basin, central China. Pet Sci. 2019;16(2):285–97. https://doi.org/10.1007/s12182-019-0307-9.

Demaison GJ, Moore GT. Anoxic environments and oil source bed genesis. Org Geochem. 1980;2(1):9–31. https://doi.org/10.1016/0146-6380(80)90017-0.

Duggen S, Croot P, Schacht U, et al. Subduction zone volcanic ash can fertilize the surface ocean and stimulate phytoplankton growth: evidence from biogeochemical experiments and satellite data. Geophys Res Lett. 2007;34(1):95–119. https://doi.org/10.1029/2006GL027522.

Er C, Zhao JZ, Wang R, et al. Controlling role of sedimentary environment on the distribution of organic-rich shale: a case study of the Chang 7 member of the Triassic Yanchang Formation: Ordos basin. Nat Gas Geosci. 2015;26(5):823–32. https://doi.org/10.11764/j.issn.1672-1926.2015.05.0823.

Fan MM. Research on sedimentary facies of Yanchang Formation in the southwest of Ordos basin (master dissertation). Xi’an: Northwest University; 2010 (in Chinese).

Fu JH, Deng XQ, Chu MJ, et al. Features of deepwater lithofacies, Yanchang Formation in Ordos basin and its petroleum significance. Acta Sedimentol Sin. 2013;31(5):928–38. https://doi.org/10.14027/j.cnki.cjxb.2013.05.011(in Chinese).

He C, Ji LM, Wu YD, et al. Characteristics of hydrothermal sedimentation process in the Yanchang Formation, south Ordos basin, China: evidence from element geochemistry. Sediment Geol. 2016;345:33–41. https://doi.org/10.1016/j.sedgeo.2016.09.001.

He C, Ji LM, Su A, et al. Source-rock evaluation and depositional environment of black shales in the Triassic Yanchang Formation, southern Ordos basin, north- central China. J Pet Sci Eng. 2019;173:899–911. https://doi.org/10.1016/j.petrol.2018.10.089.

Katz BJ. Controlling factors on source rock development- a review of productivity, preservation, and sedimentation rate. SEPM. 2005. https://doi.org/10.2110/pec.05.82.0007.

Langmann B, Zakšek K, Hort M, et al. Volcanic ash as fertiliser for the surface ocean. Atmos Chem Phys. 2010;10(8):3891–9. https://doi.org/10.5194/acp-10-3891-2010.

Lee CTA, Jiang H, Ronay E, et al. Volcanic ash as a driver of enhanced organic carbon burial in the cretaceous. Sci Rep. 2018;8(1):41–97. https://doi.org/10.1038/s41598-018-22576-3.

Lei Y, Feng QL, Gui BW. Geobiological model for organic enrichment in upper Permian Dalong Formation of Qingdingshan section at Chaohu. Anhui J Palaeogeogr. 2010;12(2):202–11 (in Chinese).

Li DL, Li RX, Zhu Z, et al. Origin of organic matter and paleo-sedimentary environment reconstruction of the Triassic oil shale in Tongchuan city, southern Ordos basin (China). Fuel. 2017;208(15):223–35. https://doi.org/10.1016/j.fuel.2017.07.008.

Li DL, Li RX, Tao X, et al. Characteristic and geological implications of major elements and rare earth elements of Triassic Chang 7 oil shale in Tongchuan city, southern Ordos basin (China). Minerals. 2018;8(4):157. https://doi.org/10.3390/min8040157.

Li YF, Shao DY, Lv HG, et al. A relationship between elemental geochemical characteristics and organic matter enrichment in marine shale of Wufeng Formation- Longmaxi Formation. Sichuan Basin Acta Pet Sin. 2015;36(12):1470–83. https://doi.org/10.7623/syxb201512002(in Chinese).

Li H. Research in characteristic of deep lacustrine sediment and tuff deposits of Yanchang Formation, upper Triassic in Ordos basin (master dissertation). Xi’an: Northwest University; 2009 (in Chinese).

Li Q. The radioactive anomaly in the deep strata and its impacts on source rocks’ evolvement in southwest Ordos basin (mater dissertation). Xi’an: Northwest University; 2007 (in Chinese).

Lin II, Hu CM, Li YH, et al. Fertilization potential of volcanic dust in the low-nutrient low-chlorophyll western north pacific subtropical gyre: satellite evidence and laboratory study. Glob Biogeochem Cycles. 2011;25(1):73. https://doi.org/10.1029/2009GB003758.

Luning S, Kolonic S, Loydell DK, et al. Reconstruction of the original organic richness in weathered Silurian shale outcrops (Murzuq and Kufra basins, southern Libya). GeoArabia. 2003;8(2):299–308.

Ma ZH, Chen QS, Shi ZW, et al. Geochemistry of oil shale from Chang 7 reservoir of Yanchang Formation in south Ordos basin and its geological significance. Geol Bull China. 2016;35(9):1550–8 (in Chinese).

Meng QT, Liu ZJ, Hu F, et al. Productivity of eocene ancient lake and enrichment mechanism of organic matter in huadian basin. J China Univ Pet. 2012;36(5):38–44. https://doi.org/10.3969/j.issn.1673-5005.2012.05.007(in Chinese).

Qiu XW. Characteristics and forming environments of tuffs in Yanchang Formaiton in Ordos basin (master dissertation). Xi’an: Northwest University; 2008 (in Chinese).

Qiu XW, Liu CY, Li YH, et al. Distribution characteristics and geological significances of tuff interlayers in Yanchang Formation of Ordos basin. Acta Sedimentol Sin. 2009;27(6):1138–46. https://doi.org/10.14027/j.cnki.cjxb.2009.06.012(in Chinese).

Qiu XW, Liu CY, Mao GZ, et al. Petrological- geochemical characteristics of volcanic ash sediments in Yanchang Formation in Ordos basin. Earth Sci J China Univ Geosci. 2011;36(1):139–50. https://doi.org/10.3799/dqkx.2011.015(in Chinese).

Qiu XW. Characteristics and dynamic settings of Yanchang period hydrocarbon-rich depression in Ordos basin, China (doctoral dissertation). Xi’an: Northwest University; 2011 (in Chinese).

Sun SS, Yao YB, Lin W. Elemental geochemical characteristics of the oil shale and the paleo-lake environment of the Tongchuan area, southern Ordos basin. Bull Mineral Pet Geochem. 2015;34(3):642–5. https://doi.org/10.3969/j.issn.1007-2802.2015.03.021(in Chinese).

Tribovillard N, Algeo TJ, Lyons T, et al. Trace metals as paleoredox and paleoproductivity proxies: an update. Chem Geol. 2006;232(1–2):12–32. https://doi.org/10.1016/j.chemgeo.2006.02.012.

Wang C, Wang Q, Chen GJ, et al. Petrographic and geochemical characteristics of the lacustrine black shales from the upper Triassic Yanchang Formation of the Ordos basin, China: implications for the organic matter accumulation. Mar Pet Geol. 2017;86:52–65. https://doi.org/10.1016/j.marpetgeo.2017.05.016.

Wang L. The recovery of the paleoproductitivty in the period of Chang 7 in Ordos basin and its control factors (mater dissertation). Xi’an: Northwest University; 2015 (in Chinese).

Wang PJ, Gao YF, Cheng RH, et al. Description of Cretaceous sedimentary sequence of the second and third member of the Qingshankou Formation recovered by CCSD-SK-I south borehole in Songliao basin: lithostratigraphy, sedimentary facies and cyclic stratigraphy. Earth Sci Front. 2009;16(2):288–313. https://doi.org/10.1016/S1872-5791(08)60080-9.

Wei H, Algeo TJ, Yu H, et al. Episodic euxinia in the changhsingian (late Permian) of south China: evidence from framboidal pyrite and geochemical data. Sediment Geol. 2015;319(15):78–97. https://doi.org/10.1016/j.sedgeo.2014.11.008.

Wignall PB, Newton R. Pyrite framboid diameter as a measure of oxygen deficiency in ancient mudrocks. Am J Sci. 1998;298(7):537–52. https://doi.org/10.2475/ajs.298.7.537.

Wignall PB, Bond DPG, Kuwahara K, et al. An 80 million year oceanic redox history from Permian to Jurassic pelagic sediments of the mino-tamba terrane, sw Japan, and the origin of four mass extinctions. Glob Planet Change. 2010;71(1–2):109–23. https://doi.org/10.1016/j.gloplacha.2010.01.022.

Wilkin RT, Barnes HL. Formation processes of framboidal pyrite. J Geochem Soc Meteorit Soc Geochim Cosmochim Acta. 1997;61(2):323–39. https://doi.org/10.1016/s0016-7037(96)00320-1.

Wilkin RT, Barnes HL, Brantley SL, et al. The size distribution of framboidal pyrite in modern sediments: an indicator of redox conditions. Geochim Cosmochim Acta. 1996;60(20):3897–912. https://doi.org/10.1016/0016-7037(96)00209-8.

Xiao RG, Zhang HC, Chen HQ, et al. Hydrothermal sedimentary rock and indicators of minerals and rocks. Earth Sci Front. 2001;8(04):379–85. https://doi.org/10.3321/j.issn:1005-2321.2001.04.018(in Chinese).

Xiong LF, Liu CY, Qiu XW, et al. Tectonic activity of late Triassic in Ordos basin and its effect on the formation of high quality source rocks. Geol Sci Technol Inf. 2015;34(2):109–114+136 (in Chinese).

Yang H, Zhang WZ. Leading effect of the seventh member high-quality source rock of Yanchang Formation in Ordos basin during the enrichment of low-penetrating oil-gas accumulation: geology and geochemistry. Geochimica. 2005;34(2):147–54 (in Chinese).

Yang H, Zhang W, Wu K, et al. Uranium enrichment in lacustrine oil source rocks of the Chang 7 member of the Yanchang Formation, Ordos basin. China J Asian Earth Sci. 2010;39(4):285–93. https://doi.org/10.1016/j.jseaes.2010.03.013.

Zhang WZ, Yang H, Peng PA, et al. The influence of late Triassic volcanism on the development of Chang 7 high grade hydrocarbon source rock in Ordos basin. Geochimica. 2009;38(6):573–82. https://doi.org/10.3321/j.issn:0379-1726.2009.06.007(in Chinese).

Zhang WZ, Yang H, Xie LQ, et al. Discovery of micro and nanofossils in high grade hydrocarbon source rocks of the Triassic Yanchang Formation Chang 7 member in Ordos basin and its scientific significance. Acta Palaeontol Sin. 2011;50(1):109–17 (in Chinese).

Zhang WZ, Yang H, Yang YH, et al. Petrology and element geochemistry and development environment of Yanchang Formation Chang 7 high quality source rock in Ordos basin. Geochmica. 2008;37(1):59–64. https://doi.org/10.19700/j.0379-1726.2008.01.008(in Chinese).

Zhang Y, Zheng S, Gao B, et al. Distribution characteristic and enrichment factors of organic matter in upper Permian Dalong Formation of Shangsi section, Guangyuan. Sichuan Basin Earth Sci. 2017a;42(6):1008–25. https://doi.org/10.3799/dqkx.2017.534(in Chinese).

Zhang WZ, Yang W, Xie LQ. Controls on organic matter accumulation in the Triassic Chang 7 lacustrine shale of the Ordos basin, central China. Int J Coal Geol. 2017b;183:38–51. https://doi.org/10.1016/j.coal.2017.09.015.