The oxo/peroxo debate: a nonheme iron perspective

JBIC Journal of Biological Inorganic Chemistry - Tập 9 - Trang 684-690 - 2004
Lawrence Que1
1Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, Minneapolis, USA

Tóm tắt

The oxygen activation mechanisms proposed for nonheme iron systems generally follow the heme paradigm in invoking the involvement of iron-peroxo and iron-oxo species in their catalytic cycles. However, the nonheme ligand environments allow for end-on and side-on dioxygen coordination and impart greater flexibility in the modes of dioxygen activation. The currently available evidence for nonheme iron-peroxo and iron-oxo intermediates is summarized and discussed in light of the ongoing discussion on the nature of the oxidant(s) in heme enzymes.

Tài liệu tham khảo

Wallar BJ, Lipscomb JD (1996) Chem Rev 96:2625–2658 Costas M, Mehn MP, Jensen MP, Que L Jr (2004) Chem Rev 104:939–986 Burger RM (1998) Chem Rev 98:1153–1169 Burger RM (2000) Struct Bonding 97:287–303 Burger RM, Kent TA, Horwitz SB, Münck E, Peisach J (1983) J Biol Chem 258:1559–1564 Burger RM, Blanchard JS, Horwitz SB, Peisach J (1985) J Biol Chem 260:15406–15409 Sam JW, Tang X-J, Peisach J (1994) J Am Chem Soc 116:5250–5256 Neese F, Zaleski JM, Zaleski KL, Solomon EI (2000) J Am Chem Soc 122:11703–11724 Absalon MJ, Wu W, Kozarich JW, Stubbe J (1995) J Am Chem Soc 34:2076–2086 Lee S-K, Nesheim JC, Lipscomb JD (1993) J Biol Chem 268:21569–21577 Lee S-K, Fox BG, Froland WA, Lipscomb JD, Münck E (1993) J Am Chem Soc 115:6450–6451 Liu KE, Valentine AM, Wang D, Huynh BH, Edmondson DE, Salifoglou A, Lippard SJ (1995) J Am Chem Soc 117:10174–10185 Shu L, Nesheim JC, Kauffmann K, Münck E, Lipscomb JD, Que L Jr (1997) Science 275:515–518 Nesheim JC, Lipscomb JD (1996) Biochemistry 35:10240–10247 Valentine AM, Stahl SS, Lippard SJ (1999) J Am Chem Soc 121:3876–3887 Brazeau BJ, Austin RN, Tarr C, Groves JT, Lipscomb JD (2001) J Am Chem Soc 123:11831–11837 Newcomb M, Shen R, Lu Y, Coon MJ, Hollenberg PF, Kopp DA, Lippard SJ (2002) J Am Chem Soc 124:6879–6886 Bollinger JM Jr, Edmondson DE, Huynh BH, Filley J, Norton J, Stubbe J (1991) Science 253:292–298 Sturgeon BE, Burdi D, Chen S, Huynh B-H, Edmondson DE, Stubbe J, Hoffman BM (1996) J Am Chem Soc 118:7551–7557 Burdi D, Willems J-P, Riggs-Gelasco P, Antholine WE, Stubbe J, Hoffman BM (1998) J Am Chem Soc 120:12910–12919 Riggs-Gelasco PJ, Shu L, Chen S, Burdi D, Huynh BH, Que L Jr, Stubbe J (1998) J Am Chem Soc 120:849–860 Tong WH, Chen S, Lloyd SG, Edmonson DE, Huynh BH, Stubbe J (1996) J Am Chem Soc 118:2107–2108 Moënne-Loccoz P, Baldwin J, Ley BA, Loehr TM, Bollinger JM Jr (1998) Biochemistry 37:14659–14663 Voegtli WC, Khidekel N, Baldwin J, Ley BA, Bollinger JM Jr, Rosenzweig AC (2000) J Am Chem Soc 122:3255–3261 Ormö M, deMaré F, Regnström K, Aberg A, Sahlin M, Ling J, Loehr T, Sanders-Loehr J, Sjöberg B-M (1992) J Biol Chem 267:8711–8714 Åberg A, Ormö M, Nordlund P, Sjöberg B-M (1993) Biochemistry 32:9845–9850 Baldwin J, Voegtli WC, Khidekel N, Moénne-Loccoz P, Krebs C, Pereira AS, Ley BA, Huynh BH, Loehr TM, Riggs-Gelasco PJ, Rosenzweig AC, Bollinger JM Jr (2001) J Am Chem Soc 123:7017–7030 Prescott AG, Lloyd MD (2000) Nat Prod Rep 17:367–383 Hanauske-Abel HM, Günzler V (1982) J Theor Biol 94:421–455 Lindblad B, Lindstedt G, Lindstedt S (1970) J Am Chem Soc 92:7446–7449 Lindblad B, Lindstedt G, Tofft M, Lindstedt S (1969) J Am Chem Soc 91:4604–4606 Borowski T, Bassan A, Siegbahn PEM (2004) Chem Eur J 10:1031–1041 Rohde J-U, In JH, Lim MH, Brennessel WW, Bukowski MR, Stubna A, Münck E, Nam W, Que L Jr (2003) Science 299:1037–1039 Lim MH, Rohde J-U, Stubna A, Bukowski MR, Costas M, Ho RYN, Münck E, Nam W, Que L Jr (2003) Proc Natl Acad Sci USA 100:3665–3670 Kaizer J, Klinker EJ, Oh NY, Rohde J-U, Song WJ, Stubna A, Kim J, Nam W, Münck E, Que L Jr (2004) J Am Chem Soc 126:472-473 Mehn MP, Fujisawa K, Hegg EL, Que L Jr (2003) J Am Chem Soc 125:7828–7842 Elkins JM, Ryle MJ, Clifton IJ, Hotopp JCD, Lloyd JS, Burzlaff NI, Baldwin JE, Hausinger RP, Roach PL (2002) Biochemistry 41:5185–5192 Price JC, Barr EW, Tirupati B, Bollinger JM Jr, Krebs C (2003) Biochemistry 42:7497–7508 Proshlyakov DA, Henshaw TF, Monterosso GR, Ryle MJ, Hausinger RP (2004) J Am Chem Soc 126:1022–1023 Riggs-Gelasco PJ, Price JC, Guyer RB, Brehm JH, Barr EW, Bollinger JM Jr, Krebs C (2004) J Am Chem Soc 126:8108–8109 Price JC, Barr EW, Glass TE, Krebs C, Bollinger JM Jr (2003) J Am Chem Soc 125:13008–13009 Gibson DT, Parales RE (2000) Curr Opin Biotechnol 11:236–243 Kauppi B, Lee K, Carredano E, Parales RE, Gibson DT, Eklund H, Ramaswamy S (1998) Structure 6:571–586 Karlsson A, Parales JV, Parales RE, Gibson DT, Eklund H, Ramaswamy S (2003) Science 299:1039–1042 Wolfe MD, Parales JV, Gibson DT, Lipscomb JD (2001) J Biol Chem 276:1945–1953 Harris DL, Loew GH (1998) J Am Chem Soc 120:8941–8948 Davydov R, Makris TM, Kofman V, Werst DE, Sligar SG, Hoffman BM (2001) J Am Chem Soc 123:1403–1415 Wertz DL, Valentine JS (2000) Struct Bonding 97:38–60 Roelfes G, Vrajmisu V, Chen K, Ho RYN, Rohde J-U, Zondervan C, la Crois RM, Schudde EP, Lutz M, Spek AL, Hage R, Feringa BL, Münck E, Que L Jr (2003) Inorg Chem 42:2639–2653 Wolfe MD, Lipscomb JD (2003) J Biol Chem 278:829–835 Wackett LP, Kwart LD, Gibson DT (1988) Biochemistry 27:1360–1367 Gibson DT, Resnick SM, Lee K, Brand JM, Torok DS, Wackett LP, Schocken MJ, Haigler BE (1995) J Bacteriol 177:2615–2621 Chen K, Que L Jr (1999) Angew Chem Int Ed 38:2227–2229 Chen K, Costas M, Kim J, Tipton AK, Que L Jr (2002) J Am Chem Soc 124:3026–3035 Chen K, Costas M, Que L Jr (2002) Dalton Trans 672–679 Bassan A, Blomberg MRA, Siegbahn PEM, Que L Jr (2002) J Am Chem Soc 124:11056–11063 Bassan A, Blomberg MRA, Siegbahn PEM (2004) J Biol Inorg Chem 9:439–452 Nam W, Ho RYN, Valentine JS (1991) J Am Chem Soc 113:7052–7054 Guajardo RJ, Hudson SE, Brown SJ, Mascharak PK (1993) J Am Chem Soc 115:7971–7977