The Pormylation of an Aromatic Nucleus by the Use of 2-Ethoxy-1,3-dithiolane

Bulletin of the Chemical Society of Japan - Tập 54 Số 7 - Trang 2120-2123 - 1981
Shigeo Jo1, Shigeo Tanimoto1, Toyonari Sugimoto1, Masaya Okano1
1Institute for Chemical Research, Kyoto University

Tóm tắt

Abstract

The reaction of various phenols with 2-ethoxy-1,3-dithiolane proceeded smoothly in the presence of BF3·Et2O to afford 1,3-dithiolan-2-ylated phenols, which were readily hydrolyzed to the corresponding aldehydes. This process was also extended to N,N-dimethylaniline and indole.

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