The Polyanilines: a Novel Class of Conducting Polymers

Springer Science and Business Media LLC - Tập 173 - Trang 283-291 - 2011
Alan G. Macdiarmid1, Arthur J. Epstein2
1Department of Chemistry, University of Pennsylvania, Philadelphia, USA
2Department of Physics and Department of Chemistry, The Ohio State University, Columbus, USA

Tóm tắt

The synthesis of polyaniline in its fully oxidized, fully reduced and selected average intermediate oxidation states is described together with the synthesis of a self-protonic acid doped polyaniline. The processing of polyaniline films and fibers by thermal stretching to give conductivities up to ∼100 S/cm is reported. Both doped and undoped polyaniline fibers have tensile strengths approaching those of commercial polymers.

Tài liệu tham khảo

J-C. Chiang and A.G. MacDiarmid, Synth. Met. 13, 193 (1986).

A.G. MacDiarmid, J-C. Chiang, A.F. Richter, N.L.D. Somasiri and A.J. Epstein, Conducting Polymers, edited by L. Alcacér (Reidel Publications, Dordrecht, 1987).

J-C. Chiang, PhD. dissertation, University of Pennsylvania, (1987).

S. Kaplan, E.M. Conwell, A.F. Richter and A.G. MacDiarmid, Synth. Met. 29, E235 (1989).

A.F. Richter, A. Ray, K.V. Ramanathan, S.K. Manohar, G.T. Furst, S.J. Opella, A.G. MacDiarmid and A.J. Epstein, Synth. Met. 29, E243 (1989).

A. Ray, Ph.D. dissertation, University of Pennsylvania, (1989).

A.G. MacDiarmid, J-C. Chiang, A.F. Richter and A.J. Epstein, Synth. Met. 18, 285 (1987).

P.M. McManus, S.C. Yang and R.J. Cushman, J. Chem. Soc. Chem. Commun. 1556 (1985).

G.E. Wnek, Synth. Met. 15, 213 (1986).

A.J. Epstein, J.M. Ginder, F. Zuo, R.W. Bigelow, H.S. Woo, D.B. Tanner, A.F. Richter, W-S. Huang and A.G. MacDiarmid, Synth. Met. 18, 303 (1987); J.M. Ginder, A.F. Richter, A.G. MacDiarmid and A.J. Epstein, Solid State Commun. 63, 97 (1987).

R.V. Gregory. W.C. Kimbrell and H.H. Kuhn, Synth. Met. 28, C-823 (1989).

S.K. Manohar, A.G. MacDiarmid and A.J. Epstein, Bull. Am. Phys. Soc. 34, 582 (1989); S.K. Manohar, A.G. MacDiarmid and A.J. Epstein, 1989, unpublished observations.

J. Yue, A.J. Epstein and A.G. MacDiarmid, to be published (1989).

A.G. Green and A.E. Woodhead, J. Chem. Soc. Trans. 97, 2388 (1910).

A.G. Green and A.E. Woodhead, J. Chem. Soc. Trans. 101, 1117 (1912).

J. Masters, S.K. Manohar, A. Ray, A.G. MacDiarmid and A.J. Epstein, unpublished results; A. Ray Ph.D. dissertation, University of Pennsylvania, (1989).

Y. Sun, A.G. MacDiarmid and A.J. Epstein, unpublished observations, (1989).

W-S. Huang, A.G. MacDiarmid and A.J. Epstein, J. Chem.Soc., Chem. Commun., 1784, (1987).

W-S. Huang, B.D. Humphrey and A.G. MacDiarmid, J. Chem. Soc. Faraday Trans. 1 82, 2385 (1986).

Y. Sun, A.G. MacDiarmid and A.J. Epstein, unpublished observations, (1989).

A.G. MacDiarmid, G.E. Asturias, D.L. Kershner, S.K. Manohar, A. Ray, E.M. Scherr, Y. Sun, X. Tang and A.J. Epstein, Polymer Preprints 30–1, 147 (1989).

X. Tang, Y. Sun and Y. Wei, Makromol. Chem., Rapid Commun., 829, 9 (1988).

J.G. Masters, Y. Sun, A.G. MacDiarmid and A.J. Epstein, unpublished observations (1989).

L.W. Shacklette, J.F. Wolfe, S. Gould and R.H. Baughman, J. Chem. Phys. 88, 3955 (1988).

M. Angelopoulos, G.E. Asturias, S.P. Ermer, A. Ray, E.M. Scherr, A.G. MacDiarmid, M. Akhtar, Z. Kiss and A.J. Epstein, Mol. Cryst. Liq. Cryst. 160, 151 (1988).

A. Andreatta, Y. Cao, J-C. Chiang, A.J. Heeger and P. Smith, Synth. Met. 26, 383 (1988).

M. Angelopoulos, A. Ray, A.G. MacDiarmid and A.J. Epstein, Synth. Met. 21, 21 (1987).

X. Tang, E. Scherr, A.G. MacDiarmid and A.J. Epstein, Bull. Am. Phys. Soc. 34, 583 (1989).

X. Tang, A.G. MacDiarmid, A.J. Epstein and Y. Wei, unpublished observations, (1989).

M.E. Jozefowicz, R. Laversanne, H.H.S. Javadi, A.J. Epstein, J.P. pouget, X. Tang and A.G. MacDiarmid, Phys. Rev. B, Rapid Commun. 39, 12958 (1989).

K.R. Cromack, M.E. Jozefowicz, J.M. Ginder, R.P. McCall, A.J. Epstein, E.M. Scherr and A.G. MacDiarmid, Bull. Am. Phys. Soc. 34, 583 (1989).

E.M. Scherr, A.G. MacDiarmid and A.J. Epstein, unpublished observations, (1989).