The Near-Infrared Combination Band Frequencies of Dioctahedral Smectites, Micas, and Illites

Cambridge University Press (CUP) - Tập 41 Số 6 - Trang 639-644 - 1993
J. L. Post1, Paul N. Noble2
1California State University, Department of Civil Engineering and Chemistry Department, Sacramento, CA, United States
2Department of Civil Engineering and Chemistry Department, California State University, Sacramento, USA

Tóm tắt

AbstractThe highest frequency near-infrared (NIR) combination bands for specimens of four species of mica—montmorillonite-beidellite, illite, chlorite, and kaolinite—were correlated with respect to Al2O3 content. A direct linear correlation was found between the combination band positions and the Al2O3 contents of the montmorillonite-beidellite series, which may be given as: ν̄ cm−1 = (5.38 ± 0.04) (% Al2O3) + (4412.8 ± 0.9). A similar linear correlation for muscovite is: ν̄ cm−1 = (6.10 ± 0.25) (% Al2O3) + (4434.1 ± 8.3).Possible NIR band interferences are shown for different mineral mixtures, along with the correlation of different illites with muscovite. No combination bands were found in the frequency region 4425 cm−1 to 4625 cm−1 for specimens in which the Al2O3 content was only in the tetrahedral layer sites.

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