Synthesis of Gallium Nitride Nanorods Through a Carbon Nanotube-Confined Reaction
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; K. E. Gansalvaes G. Carlson S. P. Rangarajan M. Benaissa M. Joseyacaman J. Mater. Chem. 6 1451 (1996);
The spread of diameters of the nanorods prepared on the basis of the carbon nanotubes has also been observed in preparing SiC nanorods [see (6)] where a simple model has been suggested to explain this phenomenon. The model may also be helpful in explaining the spread of diameters of the GaN nanorods.
Argoitia A., et al., ibid. 70, 179 (1997).
Si 3 N 4 nanorods were prepared through the reaction of carbon nanotubes with SiO under nitrogen (or ammonia) atmosphere at 1673 K for 1 hour. The reaction scheme can be expressed as 3SiO(g) + 3C(s) + 2N 2 (g) → Si 3 N 4 (s) + 3CO(g). The nanorods were 4 to 40 nm in diameter and up to 50 μm in length.
This work was supported by the Chinese National Foundation of Nature Science Research.