Sulfuric Acid from Sulfur Trioxide and Water—A Surprisingly Complex Reaction

Wiley - Tập 34 Số 12 - Trang 1313-1315 - 1995
Ralf Steudel1
1Institut für Anorganische und Analytische Chemie der Technischen Universität, D‐10623 Berlin (Germany), Telefax: Int. code + (30)314 265 19, e‐mail [email protected]‐berlin.de

Tóm tắt

On paper very simple, but in reality far more complicated—this applies to the formation of sulfuric acid in the atmosphere, which leads to the environmental problem of acid rain. In this reaction sulfur trioxide is transformed into sulfur dioxide, which reacts with water dimers to give sulfuric acid. Ab initio calculations as well as spectroscopic and kinetic studies have yielded new information on the reaction mechanism.

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