Starburst Dendrimers: Molecular‐Level Control of Size, Shape, Surface Chemistry, Topology, and Flexibility from Atoms to Macroscopic Matter
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Swift J., Gulliver's Travels (1726)
1974, Gullivers Reisen (Insel Taschenbuch 58)
Haken H., 1986, Erfolgsgeheimnisse der Natur – Synergetik: Die Lehre vom Zusammenwirken
Küppers B. O., 1987, Ordnung aus dem Chaos. Prinzipien der Selbstorganisation und Evolution des Lebens
Cramer F., 1988, Chaos und Ordnung. Die komplexe Strukture des Lebendigen
Eigen M., 1982, Evalutation Now, 11
Jaenicke R., 1984, Angew. Chem., 96, 285
1984, Angew. Chem. Int. Ed. Engl., 96, 395
1988, Angew. Chem. Int. Ed. Engl., 27, 1029
Potvin P. G., 1987, Synthesis of Macrocycles: The Design of Selective Complexing Agents (Prog. Macrocyclic Chem, 167
1979, Angew. Chem. Int. Ed. Engl., 15, 753
Angew. Chem. 1990 102
1986, Angew. Chem. Int. Ed. Engl., 27, 1039
1988, Angew. Chem. Int. Ed. Engl., 100, 104
1988, Angew. Chem. Int. Ed. Engl., 100, 109
1988, Angew. Chem. Int. Ed. Engl., 100, 760
Jurnak F. A., 1987, Biological Macromolecules and Assemblies
Spektrum Wissensch., 1985, 78
Jostkleigrewe E., 1967, Makromolekulare Chemie – Das Werk Hermann Staudingers in seiner heutigen Bedeutung
Morawetz H., 1985, Polymers. The Origin and Growth of a Science
Merrifield R. B., 1980, The Peptides
Khorana H. G., 1973, Nobel Lectures: Physiology or Medicine, 341
A term coined to denote synthetic mimicry of biological supramolecular structures with self‐assembling or covalent fixed architectures.
Nickon A., 1987, Organic Chemistry: The Name Game
Mislow K., 1989, Chemtracts‐Org. Chem., 2, 151
West B. J., 1987, Am. Sci., 75, 354
MacDonald N., 1983, Trees and Networks in Biological Models
Thompson D'Arcy W., 1961, On Growth and Farm
Vögtle F., 1981, Host Guest Complex Chemistry I–III, Top. Curr. Chem., 98
Top. Curr. Chem. 1982 101 Host Guest Complex Chemistry I–III
Top. Curr. Chem. 1984 121 Host Guest Complex Chemistry I‐III
Vögtle F., 1985, Biomimetic and Bioorganic Chemistry I‐III, Top. Curr. Chem., 128
Top. Curr. Chem. 1986 132
Top. Curr. Chem. 1986 136
Fendler J. H., 1982, Membrane Mimetic Chemistry
Flory P. J., 1953, Principles of Polymer Chemistry
Graessley W. W., 1975, Macromolecules, 8, 185
Gordon M., 1975, J. Chem. Phys., 43, 35
1963, Proc. R. Soc. (London) A, 263, 54
Buhlein E., Synthesis, 1978, 155
Tomalia D. A., 1984, 1st Society Polymer Science. Japan, Int. Polym. Conf
Tomalia D. A., 1985, 6th Biennial Carl S. Marvel Symp
D. A.Tomalia J. R.Dewald US Pat. 4507466 (1985);
US Pat. 4558 120 (1985);
US Pat. 4568737 (1986);
US Pat. 4587329 (1986);
US Pat. 4631 337 (1986);
US Pat. 4694064 (1987);
US Pat 4713975 (1987);
US Pat. 4737550 (1988);
US Pat. 4871 779 (1989);
US Pat. 4857599 (1989).
(a) This term was coined in deference to their branched (dendritic = treelike) as well as their oligomeric nature
(b) The dendrimer generation numbering system used in earlier work [62–64 67 111] designated the first starbranched species derived from the initiator core as generation 1. The present system is preferred wherein that starbranched intermediate is designated generation O. thus making it consistent with the geometric progression (cf. Section 4.2.1).
Merrifield R. E., 1989, Topological Methods in Chemistry
Cram D., 1987, Science (Washington), 238, 612
R. G.Denkewalter J. F.Kolc W. J.Lukasavage US Pat. 4410688 (1983):
1984, Chem. Abstr., 100, 103907p
Aharoni S. M., 1983, Polym. Commun., 24, 132
Newkome G. R., J. Chem. Soc. Chem. Comm., 1986, 752
Cantor G., 1915, Contributions to Transfinite Numbers
Gleick J., 1987, Chaos: Making a New Science, 99
Mandelbrot B. B., 1977, Fractals: Form, Chance and Dimension
1982, The Fractal Geometry of Nature
Kaye B. H., 1989, A Random Walk Through Fractal Dimensions
A.Cheetham K.McCormick(Smithsonian Institution. Washington D. C. USA) personal communication.
Smith P. B., 1987, Applied Polymer Analysis and Characterization, 357
D. A.Tomalia P.Kirchoff D.Downing unpublished results.
Dermer O. C., 1969, Ethyleneimine and Other Aziridines
Tomalia D. A., 1985, Alkyleneimine Polymers
D. M.Hedstrand P.Meister D. A.Tomalia unpublished results.
H.Hart personal communication.
Padias A., 1989, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem., 30, 119
Bochkarev M. N., 1988, Organomet. Chem. (USSR), 1, 115
Kim Y. H., 1988, Polym. Prep. Am. Chem. Soc. Div. Polym. Chem., 29, 310
(b) POLYGRAF is an interactive molecular mechanics/graphics program available from Molecular Simulations Inc. Pasadena CA USA. All simulations were performed on DEC Vax 8650 and Alliant FX8/8 computers. Structures were displayed on Evans & Sutherland PS330 and PS390 series graphics systems.
Pascual‐Ahuir J. L., QCPE Program No. 554
D. A.Tomalia S.Edwards D. M.Hedstrand P.Meister unpublished results.
Wilson L. R., 1989, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem, 30, 115
(a)D.Meltzer D. A.Tirell unpublished results b P. Smith unpublished results.
Ward A. L., 1938, Science of Petroleum, 1172
Kurtz S. S., 1953, Physical Chemistry of Hydrocarbons
Stryer L., 1981, Biochemistry, 724
Ross M., 1971, Contemp. Phys., 12, 333
Temperleg M. N. V., 1968, Physics of Simple Liquids
Suckling C. J., J. Chem. Soc. Chem. Commun., 1982, 661
See [86] particularly chapters 2–4.
B.Helmer D. A.Tomalia unpublished results.
D. S.Edwards C. W.Jung D. A.Tomalia unpublished results.
I. A.Tomlinson M. J.Fazio unpublished results.
Tanford C., 1980, The Hydrophobic Effect: Formation of Micelles and Biological Membranes
Mitchell D. J., J. Chem. Soc. Faraday Trans. 2, 1981, 601
Tomalia D. A., PCI Int. Appl., 0881, 178
1989, Chem. Abstr., 110, 150378x
Spektrum Wiss., 1985, 82
Cairns‐Smith A. G., 1982, Genetic Takeover and the Mineral Origins of Life
Dawkins R., 1986, New Scientist, 25, 24
Darnell J., 1986, Molecular Cell Biology, 987 ff
David I. G., 1986, Science (Washington), 240, 1443
D. A.Tomaliaet al. unpublished results.
See[137a] p. 1086.
Goethals E. J., 1989, Telechelic Polymers: Synthesis and Applications
See [137a]. pp. 774 ff.
1948, Am. Sci., 36, 51
Mazur E. G., 1974, Graphic Representation of the Periodic System During One Hundred Years
Hargittai I., 1986, Symmetry Through the Eyes of a Chemist, 5f
Tomalia D. A., 1990, Encyclopedia of Polymer Science and Engineering., 46
Hodge P., 1980, Polymer Supported Reactions in Organic Synthesis
See [137a] pp. 816f.
(a) Cationic surfactants have been successfully organized and characterized on the surfaces of anionically functionalized dendrimers. A “cooperative effect” was noted for higher‐generation PAMAM dendrimers (generations 4.5–9.5) according to photoluminescence probe techniques b) Generation‐dependent morphologies consistent with [111] were corroborated by probing with photoinduced electron‐transfer reactions on the dendrimer surfaces:N. D.Turro G.Caminati D. A.Tomalia Macromolecules(1990) in press.
One might argue that artificial protein synthesis as described byM. Mutter[4b] is one of the first efforts in this direction.
Raphael E., 1988, C. R. Acad. Sci. Paris, 307, 12
Casagrande C., 1988, C. R. Acad. Sci. Paris, 306, 1423
Maclean M., 1983, Eukaryotic Genes, Their Structure, Activity and Regulation
Ostwald W., 1917, Theoretical and Applied Colloid Chemistry: “The World of Neglected Dimensions”