Specification of Molecular Chirality
Tóm tắt
The topological analysis of chiral molecular models has provided the framework of a general system for the specification of their chirality. The application, made in and before 1956, of this system to organic‐chemical configurations is generally retained, but is redefined with respect to certain types of structure, largely in the light of experience gained since 1956 in the Beilstein Institute and elsewhere. The system is now extended to deal, on the one hand, with organic‐chemical conformations, and, on the other, with inorganic‐chemical configurations to ligancy six. Matters arising in connexion with the transference of chiral specifications from model to name are considered, notably that of the symbiosis in nomenclature of expressions of the general system and of systems of confined scope.
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Tài liệu tham khảo
The Chemical Society Burlington House Piccadilly London W. 1. Present address: 23 Woodwaye Oxhey Watford Herts. (England).
University College Gower Street London W. C. 1 (England).
Eidgenössische Technische Hochschule Zürich (Switzerland).
Cahn R. S., J. chem. Soc. (London), 1951, 612
ProfessorsS. J. Angyal H. Dahn E. L. Eliel K. Mislow andO. Th. SchmidtandDrs. K. R. Hanson S. J. Tauber andR. S. Tipson as well as (the late) ProfessorF. Richterand Dr.O. Weissbach to all of whom we are deeply grateful.
1958, Nature (London), 182, 198
Kelvin Lord, 1904, Baltimore Lectures, 436
1964, Angew. Chem. internat. Edit., 3, 512
Falk H., 1965, Mh. Chem., 96, 266
Natta G., Tetrahedron Letters, 1963, 703
Farina M., Tetrahedron Letters, 1963, 2097
Angyal S. J., J. Chem. Soc. (London), 1957, 3691
1960, International Union of Pure and Applied Chemistry, 11, 50
Mueller G. P., 1962, Ex‐perientia, 18, 404
Millen D. J., 1962, Progress in Stereochemistry
Mizushima S., 1954, Structure of Molecules and Internal Rotation
Dickerson R. E., 1964, The Proteins, 634
Bollard R. E., Proc. chem. Soc. (London), 1962, 331
McCaffery A. J., Proc. chem. Soc. (London), 1962, 388
McCaffery A. J., Chem. Commun., 1965, 132
McCaffery A. J., J. chem. Soc. (London), 1965, 2883
McCaffery A. J., Proc. chem. Soc. (London), 1963, 211
McCaffery A. J., J. chem. Soc. (London), 1965, 5094