Specification of Molecular Chirality

Wiley - Tập 5 Số 4 - Trang 385-415 - 1966
R. S. Cahn1, Christopher Kelk Ingold2, V. Prelog3
1The Chemical Society, Burlington House, Piccadilly, London, W. 1
2University College, Gower Street, London, W.C.1 (England)
3Eidgenössische Technische Hochschule, Zürich, Switzerland

Tóm tắt

AbstractThe topological analysis of chiral molecular models has provided the framework of a general system for the specification of their chirality. The application, made in and before 1956, of this system to organic‐chemical configurations is generally retained, but is redefined with respect to certain types of structure, largely in the light of experience gained since 1956 in the Beilstein Institute and elsewhere. The system is now extended to deal, on the one hand, with organic‐chemical conformations, and, on the other, with inorganic‐chemical configurations to ligancy six. Matters arising in connexion with the transference of chiral specifications from model to name are considered, notably that of the symbiosis in nomenclature of expressions of the general system and of systems of confined scope.For corrigendum see DOI:10.1002/anie.196605111

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Tài liệu tham khảo

The Chemical Society Burlington House Piccadilly London W. 1. Present address: 23 Woodwaye Oxhey Watford Herts. (England).

University College Gower Street London W. C. 1 (England).

Eidgenössische Technische Hochschule Zürich (Switzerland).

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ProfessorsS. J. Angyal H. Dahn E. L. Eliel K. Mislow andO. Th. SchmidtandDrs. K. R. Hanson S. J. Tauber andR. S. Tipson as well as (the late) ProfessorF. Richterand Dr.O. Weissbach to all of whom we are deeply grateful.

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Wiley

Tập 5 Số 4

385-415

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