Solvent Compatibility of Poly(dimethylsiloxane)-Based Microfluidic Devices

McDonald J. C., 2002, Acc. Chem. Res., 35, 499, 10.1021/ar010110q

Ng J. M. K., 2002, Electrophoresis, 23, 3473

Becker H., 2002, Talanta, 56, 287, 10.1016/S0039-9140(01)00594-X

Salimi-Moosavi H., 1997, J. Am. Chem. Soc., 119, 8717, 10.1021/ja971735f

Kakuta M., 2001, Chem. Rec., 1, 405, 10.1002/tcr.1023

Tokeshi M., 2002, Anal. Chem., 74, 1571, 10.1021/ac011111z

Burke J., 1984, AIC Book Pap

Du Y., 1996, Physical Properties of Polymers Handbook

Mark J. E., 1984, Physical Properties of Polymers

Abboud J.-L. M., 1999, Pure Appl. Chem., 71, 718

Lide D., 1994, Handbook of Chemistry and Physics, 74

Favre E., 1996, Eur. Polym. J., 32, 1188

Yoo J. S., 1999, J. Chem. Eng. Data, 44, 22

Horkay F., 1995, Polymer, 36, 4527, 10.1016/0032-3861(95)96864-5

Hedden R. C., 1999, Macromolecules, 32, 5158, 10.1021/ma990172k

Hedden R. C., 2000, Macromolecules, 33, 8684, 10.1021/ma001419c

Van Krevelen D. W., 1990, Properties of Polymers

Literature, 1996, Physical Properties of Polymers Handbook

Diachun N. A., 1910, J. Am. Chem. Soc., 32, 1032, 10.1021/ja01927a003

Chitra R., 2001, J. Chem. Phys., 115, 5530, 10.1063/1.1396676

Simonyan G. S., 2001, Kinet. Catal., 42, 478, 10.1023/A:1010513320364

Graffeuil M., 1973, J. Chim. Phys. Physicochim. Biol., 70, 1298

Deng T., 2002, Langmuir, 18, 6722, 10.1021/la020446o

Teas J. P., 1968, J. Paint Technol., 40, 25

Graham D. J., 2002, Langmuir, 18, 1527

Morra M., 1990, J. Colloid Interface Sci., 137, 24, 10.1016/0021-9797(90)90038-P

Chaudhury M. K., 1991, Langmuir, 7, 1025, 10.1021/la00053a033

Xia Y., 1998, Annu. Rev. Mater. Sci., 28, 184

Chiu D. T., 2001, Proc. Natl. Acad. Sci. U.S.A., 98, 2966

Anderson J. R., 2000, Anal. Chem., 72, 3164

Ismagilov R. F., 2001, Anal. Chem., 73, 5213

McDonald J. C., 2000, Electrophoresis, 21, 40, 10.1002/(SICI)1522-2683(20000101)21:1<27::AID-ELPS27>3.0.CO;2-C

Papra A., 2001, Langmuir, 17, 4095

Donzel C., 2001, Adv. Mater., 13, 1168, 10.1002/1521-4095(200108)13:15<1164::AID-ADMA1164>3.0.CO;2-S

Bernard A., 2001, Nat. Biotechnol., 19, 869, 10.1038/nbt0901-866

Zhang X., 1999, Sens. Actuators, A, 77, 156, 10.1016/S0924-4247(99)00189-2

Jiang X., 2002, Langmuir, 18, 2615

Barker S. L. R., 2000, Anal. Chem., 72, 4903

Arias F., 2001, J. Micromechan. Syst., 10, 112

Young R. J., 1991, Introduction to Polymers, 10.1007/978-1-4899-3176-4

Gaskell D. R., 1995, Introduction to the thermodynamics of materials

Both α and χ are temperature-dependent, dimensionless parameters that represent the enthalpy term in the Gibbs free energy equation. The difference between the parameters is that α represents the pair−pair interaction energy in a solvent−solute solution (i.e., the solvent molecule−solute molecule interaction), while χ represents two types of interactions in a polymer−solvent solution:  pair−pair interaction energy (i.e., the segment−segment interaction of the polymer) and the polymer volume and solvent volume interaction. Since χ involves volume interactions, it contains an entropic contribution, making it not as straightforward to interpret as the α term. For general discussion in this paper, however, we compare the values of α and χ directly. (For further discussion, refer to the section on Flory−Huggins Theory in:  Young, R. J.Introduction to Polymers; Chapman and Hall:  New York, 1991.)

Gilani S. S. H., 1966, J. Org. Chem., 31, 2398, 10.1021/jo01345a510

Morris D. S., 1981, J. Org. Chem., 46, 3428, 10.1021/jo00330a007

Stroock A. D., 2002, Science, 295, 651, 10.1126/science.1066238

Since, 1966, J. Org. Chem., 31

Kameoka J., 2001, Anal. Chem, 73, 1941, 10.1021/ac001533t

Roulet J.-C. V., 2002, Anal. Chem, 74, 3407

Chabinyc M. L., 2001, Anal. Chem., 73, 4498, 10.1021/ac010423z

Liang Z., 1996, J. Anal. Chem., 68, 1046

Zhan W., 2003, Anal. Chem, 75, 1238

Hebert N., 2002, Electrophoresis, 23, 3759, 10.1002/1522-2683(200211)23:21<3750::AID-ELPS3750>3.0.CO;2-X

Wang J., 2002, Talanta, 56, 231

Adams M. L., 2003, Sens. Actuators, A, 104, 31, 10.1016/S0924-4247(02)00477-6

Bowden M. a. D., D., 2003, Sens. Actuators, B, 90, 174

Bowden N., 2000, J. Phys. Chem. B, 104