Self-assembly of copper and cobalt complexes with hierarchical size and catalytic properties for hydroxylation of phenol

Nanoscale Research Letters - Tập 6 - Trang 1-7 - 2011
Huaze Dong1, Wenbo Tao2, Jianhong Bi1, Victoria Milway3, Zhiqiang Xu4, Shengyi Zhang2, Xiangchun Meng2, Wentao Bi2, Jian Li1, Meng Li2
1Department of Chemistry and Chemical Engineering, Hefei Normal University, Hefei, People's Republic of China
2School of Chemistry and Chemical Engineering, Anhui University, Hefei, People’s Republic of China
3School of Chemistry, University of Glasgow, Glasgow, UK
4SKC PowerTech, Inc., Mt. Olive, USA

Tóm tắt

A feasible and effective self-assembly method to synthesize different scale coordination polymers in highly dilute solution (from nanocrystals to microcrystals and to bulk crystals) without any blocking agent has been described. The growth of crystalline particles was controlled by removing the particles at different reaction times to interrupt the growth at the desired size. The nano and microscale particles show better catalytic conversions and selectivities in the hydroxylation of phenols than the bulk crystals.

Tài liệu tham khảo

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