Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts

American Association for the Advancement of Science (AAAS) - Tập 354 Số 6319 - Trang 1570-1573 - 2016
Joseph T. Grant1, Carlos A. Carrero1, Florian Göeltl1, Juan M. Venegas2, Philipp Müller1, Samuel P. Burt2, Sarah E. Specht1, William P. McDermott1, Alessandro Chieregato1, Ive Hermans2,1
1Department of Chemistry, University of Wisconsin–Madison, 1101 University Avenue, Madison, WI 53706, USA.
2Department of Chemical and Biological Engineering University of Wisconsin – Madison 1415 Engineering Drive Madison WI 53706 USA

Tóm tắt

Boron nitride catalysis Propene is one of the highest-volume organic chemicals produced. Propene has mainly been made from naphtha, but changes in the global supply chain are creating shortages. Direct conversion from propane, a component of natural gas, via reaction with oxygen is an attractive alternative, but existing approaches produce a large fraction of unwanted CO and CO 2 . Grant et al. report that boron nitride, normally an unreactive material, has high selectivity to catalyze the production of propene (77%) and ethene (13%). Science , this issue p. 1570

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Tài liệu tham khảo

10.1002/cssc.200900020

10.1021/cr5002436

Degnan T., Focus Catal. 2, 1 (2016).

10.1016/j.cattod.2015.02.023

10.1016/j.energy.2005.04.001

10.1021/jp9933875

10.1021/jp046011m

10.1021/cs5003417

10.1002/anie.201003238

10.1126/science.1161916

10.1002/anie.200901826

10.1021/acscatal.5b01679

10.1016/j.apcata.2007.02.006

10.1016/j.jcat.2003.10.007

10.1039/c3cy00625e

10.1016/j.jcat.2005.05.025

10.1039/C5CC00588D

10.1016/S0926-860X(01)00944-9

10.1016/j.apcata.2006.05.029

10.1038/nmat3439

10.1016/j.cattod.2007.05.009

10.1006/jcat.1999.2510

10.1038/ncomms3541

10.1063/1.1667278

10.1039/c2nr32201c

10.1126/science.269.5226.966

10.1039/C3CS60260E

10.1021/jp3036583

10.1021/ja3080665

10.1038/srep29498

10.1103/PhysRevB.47.558

10.1103/PhysRevB.59.1758

10.1002/cphc.201300130

10.1021/jp071409e

10.1021/cs200055d

10.1002/1521-3773(20010601)40:11<2066::AID-ANIE2066>3.0.CO;2-I

10.1103/PhysRevB.50.17953

10.1103/PhysRevLett.77.3865

10.1002/jcc.20495

10.1063/1.2404663