Rotational analysis of the 0 band of the <i>A</i>̃ 3<i>E</i>–<i>X</i>̃ 3<i>A</i>2 system of methylnitrene

Journal of Chemical Physics - Tập 96 Số 2 - Trang 919-926 - 1992
C. R. Brazier1, P. G. Carrick1, P. F. Bernath2
1Phillips Laboratory/RKFE, Propulsion Directorate, Edwards Air Force Base, California 93523
2Department of Chemistry, University of Arizona, Tucson, Arizona 85721

Tóm tắt

The optical emission spectrum of the methylnitrene radical has been observed at a resolution of 0.07 cm−1. Transitions to subbands with K up to 3 in the X̃ 3A2 ground state were observed and a full rotational analysis carried out. Comparison of the structural information with the highest level theoretical calculations shows agreement to within the estimated error.

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Tài liệu tham khảo

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