Responsive Supramolecular Polymers Based on the Bis[alkynylplatinum(II)] Terpyridine Molecular Tweezer/Arene Recognition Motif

Angewandte Chemie - Tập 126 Số 24 - Trang 6204-6208 - 2014
Yu‐Kui Tian1, Yonggang Shi1, Zhishuai Yang1, Feng Wang1
1Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

Tóm tắt

AbstractSupramolecular polymers are constructed based on the novel bis[alkynylplatinum(II)] terpyridine molecular tweezer/pyrene recognition motif. Successive addition of anthracene as the diene and cyano‐functionalized dienophile triggers the reversible supramolecular polymerization process, thus advancing the concept of utilizing Diels–Alder chemistry to access stimuli‐responsive materials in compartmentalized systems.

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