Reactions of N2(A3Σ)

International Journal of Chemical Kinetics - Tập 20 Số 1 - Trang 75-92 - 1988
Michael F. Golde1
1Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania, 15260

Tóm tắt

AbstractN2(A3Σ), the lowest electronically excited state of N2, has a long and distinguished history due to its role in nitrogen discharges and the nitrogen afterglow. Recently, the production of N2(A) via photolysis and chemiluminescent reactions has been newly explored, and new facets of its reactivity have been uncovered. N2(A) is unusual, in that its deactivation probability in collision with small molecules spans many orders of magnitude, and is frequently strongly dependent on the vibrational content of N2(A). This behavior and the observed product channels can be understood in terms of a simple model for the energy transfer process. Brief comparison with reactions of related species is made.

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