Preparation and properties of a salt‐resistant superabsorbent polymer

Wiley - Tập 93 Số 6 - Trang 2532-2541 - 2004
Songmei Ma1, Mingzhu Liu1, Zhenbin Chen1
1Department of Chemistry, Lanzhou University, Lanzhou 730000, China

Tóm tắt

AbstractCrosslinked sodium polyacrylate was prepared by solution polymerization with N,N‐methylene‐bisacrylamide (bisAM) as crosslinking agent; it was subsequently surface‐crosslinked by ethylene glycol diglycidyl ether (EGDE) and then was modified with inorganic salt to obtain a superabsorbent with water absorbency in 0.9 wt % NaCl aqueous solution at atmosphere and applied pressure (P ≈ 2 × 103 Pa) of 55 and 20 g.g−1, respectively. Moreover, it also had excellent hydrogel strength. The effects of reaction temperature, reaction time, neutralization degree (ND) of acrylic acid, amount of initiator, crosslinking agent, and surface‐crosslinking agent, mass ratio of inorganic salt to initial superabsorbent, molar ratio of sodium aluminate (NaAlO2) to potassium dihydrogen hyphosphate (KH2PO4) on water absorbency (WA) in 0.9 wt % NaCl aqueous, and the hydrogel modulus were investigated and optimized. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2532–2541, 2004

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Tài liệu tham khảo

10.1021/bk-1994-0573

10.1002/app.1376

10.1002/app.1616

10.1002/app.1993.070470114

Yoshio I.;Katsuhiro K.;Hitoshi T.;Teruaki F.Eur. Pat. 0454497A2 1991.

Liu M. Z., 1996, Chin J Polym Sci, 14, 48

10.1002/app.1990

Liu M. Z., 2002, Chin J Appl Chem, 19, 455

Smith S. J.;Lind E. J.U.S. Pat. 5 399 591 1995.

10.1016/S0168-3659(99)00238-2

Flory P. J., 1953, Principles of Polymer Chemistry

10.1016/S0032-3861(01)00723-6

10.1002/(SICI)1097-4628(19980711)69:2<229::AID-APP3>3.0.CO;2-P