Plasma chemical vapor deposition of TiN

Plasma Chemistry and Plasma Processing - Tập 4 - Trang 147-161 - 1984
Shizhi Li1, Wu Huang1, Hongshun Yang1, Zhongshu Wang1
1Department of Mechanical Engineering, Qingdoa, Shandong Institute of Chemical Engineering, Qingdao, China

Tóm tắt

Experiments indicate that the temperature in chemical vapor deposition (CVD) of TiN can be decreased from about 1000°C in conventional CVD to about 500°C by the application of a D.C. nonequilibrium plasma. The hardness of the TiN film is greater than 2000 kg/mm2 (Vickers). The effect of pressure, ratio of gas mixture, and discharge parameters on the film deposition rate, its hardness, and microstructures has been studied.

Tài liệu tham khảo

Handbook of Thin Film Technology, L. I. Maissel and R. Glang, eds., McGraw-Hill, New York (1970). Deposition Technologies for Films and Coatings, R. F. Bunshahet al., eds., Noyes Publ., Park Ridge, New Jersey (1982). D. Küpper, Proc. 7th Int. Conf. CVD (1979), p. 159. K. R. Linger, Proc. Conf. Ion Plating Appl. Technol. (1977), p. 223. F. J. Hazlewoodet al., Proc. Conf. Ion Plating Appl. Technol. (1977), p. 243. Mitsuharu Konumaet al., J. Less-Common Met. 75, 1 (1982). N. J. Archer,Thin Solid Films 80, 221 (1981). N. J. Archer,Surf. J. 14, 8 (1982). Wang Shinyuan,J. Shandong Chem. Eng. Inst. No. 1, 48 (1980) (in Chinese). C. Politiset al., Proc. 7th Int. Conf. CVD (1979), 289. B. A. Movchanet al., Phys. Met. Metallogr. 28, 653 (1969) (in Russian). J. R. Peterson,J. Vac. Sci. Technol. 11, 715 (1974). Subhash, K. Naik,Planseeber. Pulvermetall. 25, 32 (1977). H. Yasuda inThin Film Processes, J. L. Vossen and W. Kern, eds., Academic Press, New York (1978), p. 361. Kobayashi,Low-Temperature Plasma Chemistry, K. Hozumi, ed., Nankodo Co. Ltd., Tokyo (1976), p. 59 (in Japanese). S. \(Ve\hat prek\), J. Cryst. Growth 9, 266 (1971). S. \(Ve\hat prek\), Top. Curr. Chem. 56, 139 (1975).