Oxidation of Dilute Benzene in an Alumina Hybrid Plasma Reactor at Atmospheric Pressure

Plasma Chemistry and Plasma Processing - Tập 19 - Trang 383-394 - 1999
A. Ogata1, K. Yamanouchi1, K. Mizuno1, S. Kushiyama1, T. Yamamoto2
1Ibaraki, Japan
2Osaka Prefecture University, Osaka, Japan

Tóm tắt

The combination of plasma discharge and adsorption was examined for oxidation of dilute benzene in air in a plasma reactor packed with a mixture of BaTiO 3 pellets and porous Al 2 O 3 pellets (i.e., an alumina hybrid reactor). The oxidative decomposition of benzene was enhanced by the benzene concentrating on the Al 2 O 3 pellets. Furthermore, there was a higher selectivity to CO 2 in the products from the hybrid than from a plasma reactor packed with BaTiO 3 pellets alone. The presence of the Al 2 O 3 pellets suppressed the formation of N 2 O.

Từ khóa


Tài liệu tham khảo

E. J. Clothiaux, J. A. Koropchak, and R. R. Moore, Plasma Chem. Plasma Process. 4, 15 (1984).

T. Yamamoto, K. Ramanathane, P. A. Lawless, D. S. Ensor, J. R. Newsome, N. Plaks, and G. H. Ramsey, IEEE Trans. Ind. Appl. 28, 528 (1992).

C. M. Nunez, G. H. Ramsey, W. H. Ponder, J. H. Abbott, L. E. Hamel, and P. H. Kariher, Air Waste 43, 242 (1993).

D. Evance, L. A. Rosocha, G. K. Anderson, J. J. Coogan, and M. J. Kushner, J. Appl. Phys. 74, 5378 (1993).

T. Oda, A. Kumada, K. Tanaka, T. Takahashi, and S. Masuda, J. Electrostat. 35, 93 (1995).

H. Kohno, M. Tamura, A. Shibuya, S. Honda, A. A. Berezin, and J. S. Chang, Conf. Rec. 1995 IEEE IAS Ann. Meet. (1995), pp. 1445–1452.

T. Yamamoto, K. Mizuno, I. Tamori, A. Ogata, M. Nifuku, M. Michalska, and G. Prieto, IEEE Trans. Ind. Appl. 32, 100 (1996).

R. G. Tonkyn, S. E. Barlow, and T. M. Orlando, J. Appl. Phys. 80, 4877 (1996).

M. Nifuku, M. Horvath, J. Bodnar, G. Zhang, T. Tanaka, E. Kiss, G. Woynarovich, and H. Katoh, J. Electrostat. 40, 41, 687 (1997).

S. Futamura, A. H. Zhang, and T. Yamamoto, J. Electrostat. 42, 51 (1997).

A. Ogata, N. Shintani, K. Mizuno, S. Kushiyama, and T. Yamamoto, Conf. Rec. 1997 IEEE IAS Annu. Meet. (1997), pp. 1975–1982.

A. Ogata, K. Mizuno, S. Kushiyama, and T. Yamamoto, Plasma Chem. Plasma Process. 18, 363 (1998).

V. N. Filimonov, Yu. N. Lopatin, and D. A. Sukhov, Kinet. Katal. 10, 458 (1969).

A. Oumghar, J. C. Legrand, A. M. Diamy, and N. Turillon, Plasma Chem. Plasma Process. 15, 87 (1995).