Tóm tắt
The new mechanics of the atom introduced by Heisenberg may be based on the assumption that the variables that describe a dynamical system do not obey the commutative law of multiplication, but satisfy instead certain quantum conditions. One can build up a theory without knowing anything about the dynamical variables except the algebraic laws that they are subject to, and can show that they may be represented by matrices whenever a set of uniformising variables for the dynamical system exists. It may be shown, however (see 3), that there is no set of uniformising variables for a system containing more than one electron, so that the theory cannot progress very far on these lines. A new development of the theory has recently been given by Schrödinger. Starting from the idea that an atomic system cannot be represented by a trajectory,
i. e
., by a point moving through the co-ordinate space, but must be represented by a wave in this space, Schrödinger obtains from a variation principle a differential equation which the wave function ψ must satisty. This differential equation turns out to be very closely connected with the Hamiltonian equation which specifies the system, namely, if H (
q
r
,
P
r
- W = 0 is the Hamiltonian equation of the system, where the
q
r
,
P
r
are canonical variables, then the wave equation for ψ is {H(
q
r
,
ih
∂/∂
q
) - W} ψ = 0.
