On the structure of molybdenum diselenide and disulfide

Zeitschrift fur Anorganische und Allgemeine Chemie - Tập 540 Số 9-10 - Trang 15-17 - 1986
K. D. Bronsema1, J. L. de Boer2, F. Jellinek2
1AKZO Corporate Research, Velperweg 76, Arnhem, Niederlande
2Laboratorium voor Anorganische Chemie, Rijksuniversiteit, Nijenborgh 16, 9747 AG Groningen, Niederlande

Tóm tắt

AbstractThe crystal structure of MoSe2 has been refined from single‐crystal X‐ray diffraction data. MoSe2 is isotypic with hexagonal MoS2 (C7 type); a = 3.289(1) Å, c = 12.927(4) Å, z(Se) = 0.6210(3). It is pointed out that the structure of MoS2 is incorrectly given in many books, although it had already been correctly reported by Dickinson and Pauling [4]. Corrected interatomic distances are given; the trigonal prism about Mo is almost regular.

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Tài liệu tham khảo

Coehoorn R.: Dissertation Groningen1985.

10.1107/S0365110X6300311X

Kalikhman V. L., 1973, Izv. Akad. Nauk SSSR, Neorg. Mater., Ser. Khim., 9, 923

1973, Inorg. Mater., 9, 826

10.1021/ja01659a020

Yamaguti T., 1932, Proc. Phys. Math. Soc. Jpn., 14, 57

Klein Haneveld A. J.: Dissertation Groningen1970.

10.1107/S0365110X61002084

10.1139/v61-110

Ewald P. P., Strukturbericht 1913–1928, Z. Kristallogr., Ergänzungsband, 1931, 164

Wyckoff R. W. G., 1963, Crystal Structures, 280

Hulliger F., 1976, Structural Chemistry of Layer‐Type Phases, 237, 10.1007/978-94-010-1146-4

Ernst Th., 1955, Zahlenwerte und Funktionen, 34

10.1002/zaac.19643280514