Nucleoside syntheses, XXII1)Nucleoside synthesis with trimethylsilyl triflate and perchlorate as catalysts

Wiley - Tập 114 Số 4 - Trang 1234-1255 - 1981
Helmut Vorbrüggen1, Konrad Krolikiewicz1, Bärbel Bennua1
1Forschungslaboratorien der Schering Aktiengesellschaft, Postfach 65 03 11, D-1000 Berlin 65

Tóm tắt

AbstractThe novel Lewis acids (CH3)3SiOSO2CF3(3), (CH3)5SiOSO2C4F9(6), and (CH3)3SiClO4(4) are highly selective and efficient Friedel‐Crafts catalysts for nucleoside formation form silylated heterocycles and peracylated sugars as well as for rearrangements of persilylated protected nucleosides. With basic silylated heterocycles these new catalysts give much higher yields of the naturalN‐1‐nucleosides than with SnCl4.

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