Molecular and crystal structure of 3,7-di(2-propenyl)-1,5-diphenyl-3,7-diazabicyclo[3.3.1]-nonan-9-one complexed with copper(II) chloride

Chemistry of Heterocyclic Compounds - Tập 32 - Trang 661-665 - 1996
S. Z. Vatsadze1, S. E. Sosonyuk1, N. V. Zyk1, K. A. Potekhin1, O. I. Levina1, Yu. T. Struchkov1, N. S. Zefirov1
1M. V. Lomonosov Moscow State University, Moscow

Tóm tắt

We have investigated the molecular and crystal structure of 3, 7-di(2-propenyl)-1, 5-diphenyl-3, 7-diazabicyclo[3.3.1]nonan-9-one complexed with copper(II) chloride. We have shown for the first time that the reason for the distortion of the coordination polyhedron of the metal is the interaction of the substituents at the nitrogen atoms with the halogen atoms.

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