Molecular and crystal structure of 3,7-di(2-propenyl)-1,5-diphenyl-3,7-diazabicyclo[3.3.1]-nonan-9-one complexed with copper(II) chloride
Tóm tắt
We have investigated the molecular and crystal structure of 3, 7-di(2-propenyl)-1, 5-diphenyl-3, 7-diazabicyclo[3.3.1]nonan-9-one complexed with copper(II) chloride. We have shown for the first time that the reason for the distortion of the coordination polyhedron of the metal is the interaction of the substituents at the nitrogen atoms with the halogen atoms.
Tài liệu tham khảo
S. Z. Vatsadze. N. V. Zyk R. D. Rakhimov, K. P. Butin and N. S. Zefirov, Izv. Akad. Nauk, Ser. Khim., No. 3, 456(1995).
U. Schoen, W. Kehrbach, G. Buschmann, U. G. Kuehl, and D. Ziegler, Eur. Pat. App EP 306871; Chem. Abstr.,11, 78039 (1989).
N. Paroczai and E. Karpati, Pharmacol. Res.,24, 149 (1991).
Z. B. Zhang, C. R. Follmer, J. S. M. Sarma, F. Chen, and B. N. Singh, J. Pharmacol. Exp. Ther.,263, 40 (1992).
M. Paroczai, E. Karpati, R. Marco, and V. Kecskemeti, Pharmacol. Res.,25, 75 (1992).
C. L. Chen, S. Sangiah, K. D. Berlin, G. L. Garrison, W. Dunn, Y. Nan, B. J. Scherlag, and R. Lazzara, Res. Commun. Chem. Pathol. Pharmacol.,78, 3 (1992).
C. Takanaka, J. S. M. Sarma, and B. N. Singh, J. Cardiovasc. Pharmacol.,19, 290 (1992).
L. S. Childers, K. Folting, L. J. Merrit, and W. Streib, Acta Crystallogr. Sect. B,31, 924 (1975).
O. I. Levina, K. A. Potekhin, and E. N. Kurkutova, Dokl. Akad. Nauk,289, 876 (1986).
H. Stetter and R. Merten, Chem. Ber.,90, 868 (1957).
G. D. Hosken and R. D. Hancock, J. Chem. Soc. Chem. Commun., No. 11, 1363 (1994).
M. Zh. Buranbaev, Yu. P. Gladii, T. T. Omarov, A. Sh. Gubasheva, V. A. Palyulin, and N. S. Zefirov, Zh. Strukt. Khim.,31, 189 (1990).
S. Z. Vatsadze, Dissertation in competition for the academic degree of Candidate of the Chemical Sciences [in Russian], MGU, Moscow (1995).
F. H. Allen O. Kennard, and P. G. Watson, J. Chem. Soc. Perkin Trans. II, No. 12, S1 (1987).
A. G. Orpen, L. Brammer, and F. H. Allen, J. Chem. Soc. Dalton Trans., No. 12, S1 (1989).
S. S. Batsanov, Experimental Principles of Structural Chemistry [in Russian], Izdat. Standartov, Moscow (1986), p. 120.