Modified silica surface by phenylboronic acid derivatives as effective sugar sensor

Central European Journal of Chemistry - Tập 7 - Trang 697-701 - 2009
Joanna Kurczewska1, Grzegorz Schroeder1
1Faculty of Chemistry, Adam Mickiewicz University, Poznań, Poland

Tóm tắt

Silica surface was modified with phenylboronic acid derivatives. The structures of the functionalized supports were characterized by FT-IR spectroscopy, 13C CP/MAS NMR spectrometry, elemental and thermogravimetric analysis. The solid supports were effectively applied as artificial receptors for sugars in aqueous solutions. Alizarin Red S. (ARS) was used to detect colour change upon carbohydrate (sugar) binding. The association constants of the supports studied-ARS complex and the functionalized silica-sugar (glucose) complex were calculated. The parameters obtained were comparable with those for the phenylboronic acids used for the silica gel modification. The competitive binding of the functionalized silica surface with ARS and sugar were studied by UV/VIS measurements.

Tài liệu tham khảo

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