Iron and Nickel Complexes Containing β‐Diketiminato Ligands with Thioether Tethers

Zeitschrift fur Anorganische und Allgemeine Chemie - Tập 635 Số 2 - Trang 312-316 - 2009
S. Pfirrmann1, Christian Limberg2, Elke Hoppe1
1Institut für Chemie der Humboldt‐Universität, Brook‐Taylor‐Str. 2, 12489 Berlin, Germany
2Institut für Chemie der Humboldt‐Universität, Brook‐Taylor‐Str. 2, 12489 Berlin, Germany, Fax: +49‐(0)30‐20936966

Tóm tắt

AbstractA novel β‐diketiminato ligand precursor, LH (II), containing thioether tethers was synthesized by the reaction of acetylacetone and 2‐methylthioaniline. II was deprotonated and used in the synthesis of two iron(II) complexes, [LFeCl] (1), and [LFeOTf] (2), and one nickel(II) complex, [LNiBr] (3). All three compounds were characterized by means of single crystal X‐ray diffraction and their structures are discussed.

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Thông tin xuất bản

Zeitschrift fur Anorganische und Allgemeine Chemie

Tập 635 Số 2

312-316

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