Kỹ thuật Phá Mẫu Bằng Laser Hồng Ngoại Kết Hợp Với Hệ Thống Hút Chân Không Để Lấy Mẫu Dấu Vân

American Chemical Society (ACS) - Tập 28 - Trang 1958-1964 - 2017
Fabrizio Donnarumma1, Eden E. Camp1, Fan Cao1, Kermit K. Murray1
1Department of Chemistry, Louisiana State University, Baton Rouge, USA

Tóm tắt

Kỹ thuật phá mẫu bằng laser hồng ngoại kết hợp với hệ thống hút chân không đã được sử dụng để thu thập vật liệu từ các dấu vân được để lại trên bề mặt có độ xốp và độ nhám khác nhau. Phá mẫu bằng laser ở bước sóng 3 μm được thực hiện theo chế độ phản xạ kèm theo việc thu giữ các sản phẩm bị bắn ra bằng một bộ lọc kết nối với hệ thống hút chân không. Việc phá mẫu và thu giữ các tiêu chuẩn từ dấu vân đã được khẳng định trên các bề mặt kính, nhựa, nhôm và bìa cứng. Sử dụng kỹ thuật ion hóa bằng giải hấp trợ khuôn (MALDI), đã có thể phát hiện caffeine sau khi thêm vào với lượng chỉ từ 1 ng. Việc phát hiện chất bôi trơn bao cao su và các peptide kháng khuẩn từ một loại kem sát khuẩn cũng đã được thực hiện. Ngoài ra, việc phát hiện chất nổ từ các dấu vân để lại trên bề mặt nhựa cũng như từ việc để trực tiếp trên cùng một bề mặt bằng kỹ thuật sắc ký khí - khối phổ (GC-MS) đã được chứng minh.

Từ khóa

#phá mẫu bằng laser hồng ngoại #hút chân không #dấu vân tay #ion hóa bằng giải hấp trợ khuôn #phát hiện chất nổ #sắc ký khí - khối phổ

Tài liệu tham khảo

Hazarika, P., Russell, D.A.: Advances in fingerprint analysis. Angew. Chem. Int. Ed. Engl. 51, 3524–3531 (2012) Wei, Q., Zhang, M., Ogorevc, B., Zhang, X.: Recent advances in the chemical imaging of human fingermarks (a review). Analyst 141, 6172–6189 (2016) Bandey, H.: Fingermark visualisation manual. Home Office Center for Applied Science and Technology (CAST): Sandridge, UK (2014) Sodhi, G., Kaur, J.: Powder method for detecting latent fingerprints: a review. Forensic Sci. Int. 120, 172–176 (2001) Payne, G., Reedy, B., Lennard, C., Comber, B., Exline, D., Roux, C.: A further study to investigate the detection and enhancement of latent fingerprints using visible absorption and luminescence chemical imaging. Forensic Sci. Int. 150, 33–51 (2005) Becue, A.: Emerging fields in fingermark (meta) detection—a critical review. Anal. Methods 8, 7983–8003 (2016) Bailey, M.J., Bright, N.J., Croxton, R.S., Francese, S., Ferguson, L.S., Hinder, S., Jickells, S., Jones, B.J., Jones, B.N., Kazarian, S.G.: Chemical characterization of latent fingerprints by matrix-assisted laser desorption ionization, time-of-flight secondary ion mass spectrometry, mega electron volt secondary mass spectrometry, gas chromatography/mass spectrometry, X-ray photoelectron spectroscopy, and attenuated total reflection Fourier transform infrared spectroscopic imaging: an intercomparison. Anal. Chem. 84, 8514–8523 (2012) Ifa, D.R., Manicke, N.E., Dill, A.L., Cooks, G.: Latent fingerprint chemical imaging by mass spectrometry. Science 321, 805–805 (2008) Asano, K.G., Bayne, C.K., Horsman, K.M., Buchanan, M.V.: Chemical composition of fingerprints for gender determination. J. Forensic Sci. 47, 805–807 (2002) Mou, Y., Rabalais, J.W.: Detection and identification of explosive particles in fingerprints using attenuated total reflection‐Fourier transform infrared spectromicroscopy. J. Forensic Sci. 54, 846–850 (2009) Chen, T., Schultz, Z.D., Levin, I.W.: Infrared spectroscopic imaging of latent fingerprints and associated forensic evidence. Analyst 134, 1902–1904 (2009) Wolstenholme, R., Bradshaw, R., Clench, M.R., Francese, S.: Study of latent fingermarks by matrix-assisted laser desorption/ionisation mass spectrometry imaging of endogenous lipids. Rapid Commun. Mass Spectrom. 23, 3031–3039 (2009) Kaplan‐Sandquist, K.A., LeBeau, M.A., Miller, M.L.: Evaluation of four fingerprint development methods for touch chemistry using matrix‐assisted laser desorption ionization/time‐of‐flight mass spectrometry. J. Forensic Sci. 60, 611–618 (2015) Francese, S., Bradshaw, R., Ferguson, L., Wolstenholme, R., Clench, M., Bleay, S.: Beyond the ridge pattern: multi-informative analysis of latent fingermarks by MALDI mass spectrometry. Analyst 138, 4215–4228 (2013) Sundar, L., Rowell, F.: Detection of drugs in lifted cyanoacrylate-developed latent fingermarks using two laser desorption/ionisation mass spectrometric methods. Analyst 139, 633–642 (2014) Lauzon, N., Dufresne, M., Chauhan, V., Chaurand, P.: Development of laser desorption imaging mass spectrometry methods to investigate the molecular composition of latent fingermarks. J. Am. Soc. Mass Spectrom. 26, 878–886 (2015) Guinan, T., Della Vedova, C., Kobus, H., Voelcker, N.H.: Mass spectrometry imaging of fingerprint sweat on nanostructured silicon. Chem. Commun. 51, 6088–6091 (2015) Muramoto, S., Sisco, E.: Strategies for potential age dating of fingerprints through the diffusion of sebum molecules on a nonporous surface analyzed using time-of-flight secondary ion mass spectrometry. Anal. Chem. 87, 8035–8038 (2015) Venter, A., Nefliu, M., Graham Cooks, R.: Ambient desorption ionization mass spectrometry. TrAC Trends Anal. Chem. 27, 284–290 (2008) Musah, R.A., Cody, R.B., Dane, A.J., Vuong, A.L., Shepard, J.R.: Direct analysis in real time mass spectrometry for analysis of sexual assault evidence. Rapid Commun. Mass Spectrom. 26, 1039–1046 (2012) Rowell, F., Seviour, J., Lim, A.Y., Elumbaring-Salazar, C.G., Loke, J., Ma, J.: Detection of nitro-organic and peroxide explosives in latent fingermarks by DART-and SALDI-TOF-mass spectrometry. Forensic Sci. Int. 221, 84–91 (2012) Brown, H., Oktem, B., Windom, A., Doroshenko, V., Evans-Nguyen, K.: Direct analysis in real time (DART) and a portable mass spectrometer for rapid identification of common and designer drugs on-site. Forensic Chem. 1, 66–73 (2016) Groeneveld, G., de Puit, M., Bleay, S., Bradshaw, R., Francese, S.: Detection and mapping of illicit drugs and their metabolites in fingermarks by MALDI MS and compatibility with forensic techniques. Sci. Rep. 5, (2015) Gassner, A.-L., Weyermann, C.: LC-MS method development and comparison of sampling materials for the analysis of organic gunshot residues. Forensic Sci. Int. 264, 47–55 (2016) van Oorschot, R.A., Ballantyne, K.N., Mitchell, R.J.: Forensic trace DNA: a review. Investig. Genet. 1, 14 (2010) Romolo, F.S., Cassioli, L., Grossi, S., Cinelli, G., Russo, M.V.: Surface-sampling and analysis of TATP by swabbing and gas chromatography/mass spectrometry. Forensic Sci. Int. 224, 96–100 (2013) Clemons, K., Wiley, R., Waverka, K., Fox, J., Dziekonski, E., Verbeck, G.F.: Direct analyte‐probed nanoextraction coupled to nanospray ionization-mass spectrometry of drug residues from latent fingerprints. J. Forensic Sci. 58, 875–880 (2013) Girod, A., Weyermann, C.: Lipid composition of fingermark residue and donor classification using GC/MS. Forensic Sci. Int. 238, 68–82 (2014) Michalski, S., Shaler, R., Dorman, F.L.: The evaluation of fatty acid ratios in latent fingermarks by gas chromatography/mass spectrometry (GC/MS) analysis. J. Forensic Sci. 58, (2013) Zhang, T., Chen, X., Yang, R., Xu, Y.: Detection of methamphetamine and its main metabolite in fingermarks by liquid chromatography–mass spectrometry. Forensic Sci. Int. 248, 10–14 (2015) Russo, R.E., Mao, X., Gonzalez, J.J., Zorba, V., Yoo, J.: Laser ablation in analytical chemistry. Anal. Chem. 85, 6162–6177 (2013) Cahill, J.F., Kertesz, V., Van Berkel, G.J.: Laser dissection sampling modes for direct mass spectral analysis. Rapid Commun. Mass Spectrom. 30, 611–619 (2016) Cahill, J.F., Kertesz, V., Van Berkel, G.J.: Characterization and application of a hybrid optical microscopy/laser ablation liquid vortex capture/electrospray ionization system for mass spectrometry imaging with sub-micrometer spatial resolution. Anal. Chem. 87, 11113–11121 (2015) Limbeck, A., Galler, P., Bonta, M., Bauer, G., Nischkauer, W., Vanhaecke, F.: Recent advances in quantitative LA-ICP-MS analysis: challenges and solutions in the life sciences and environmental chemistry. Anal. Bioanal. Chem. 407, 6593–6617 (2015) Little, M.W., Laboy, J., Murray, K.K.: Wavelength dependence of soft infrared laser desorption and ionization. J. Phys. Chem. C 111, 1412–1416 (2007) Park, S.G., Murray, K.K.: Infrared laser ablation sample transfer for MALDI imaging. Anal. Chem. 84, 3240–3245 (2012) Donnarumma, F., Cao, F., Murray, K.K.: Laser ablation with vacuum capture for MALDI mass spectrometry of tissue. J. Am. Soc. Mass Spectrom. 27, 108–116 (2016) Park, S.G., Murray, K.K.: Infrared laser ablation sample transfer for on-line liquid chromatography electrospray ionization mass spectrometry. J. Mass Spectrom. 47, 1322–1326 (2012) Donnarumma, F., Murray, K.K.: Laser ablation sample transfer for localized LC‐MS/MS proteomic analysis of tissue. J. Mass Spectrom. 51, 261–268 (2016) Allaoui, S., Aboura, Z., Benzeggagh, M.: Effects of the environmental conditions on the mechanical behavior of the corrugated cardboard. Compos. Sci. Technol. 69, 104–110 (2009) Croxton, R.S., Baron, M.G., Butler, D., Kent, T., Sears, V.G.: Variation in amino acid and lipid composition of latent fingerprints. Forensic Sci. Int. 199, 93–102 (2010) Hartzell-Baguley, B., Hipp, R.E., Morgan, N.R., Morgan, S.L.: Chemical composition of latent fingerprints by gas chromatography–mass spectrometry—an experiment for an instrumental analysis course. J. Chem. Educ. 84, 689–691 (2007) Fuchs, B., Süß, R., Schiller, J.: An update of MALDI-TOF mass spectrometry in lipid research. Prog. Lipid Res. 49, 450–475 (2010) Pokhrel, D., Viraraghavan, T.: Treatment of pulp and paper mill wastewater—a review. Sci. Total Environ. 333, 37–58 (2004) Vogel, A., Venugopalan, V.: Mechanisms of pulsed laser ablation of biological tissues. Chem. Rev. 103, 577–644 (2003) Campbell, G.P., Gordon, A.L.: Analysis of condom lubricants for forensic casework. J. Forensic Sci. 52, 630–642 (2007) Maynard, P., Allwell, K., Roux, C., Dawson, M., Royds, D.: A protocol for the forensic analysis of condom and personal lubricants found in sexual assault cases. Forensic Sci. Int. 124, 140–156 (2001) Causin, V.: Polymers on the crime scene: How can analytical chemistry help to exploit the information from these mute witnesses? Anal. Methods 2, 792–804 (2010) Bradshaw, R., Wolstenholme, R., Blackledge, R.D., Clench, M.R., Ferguson, L.S., Francese, S.: A novel matrix‐assisted laser desorption/ionisation mass spectrometry imaging based methodology for the identification of sexual assault suspects. Rapid Commun. Mass Spectrom. 25, 415–422 (2011) Picardo, M., Ottaviani, M., Camera, E., Mastrofrancesco, A.: Sebaceous gland lipids. Dermatoendocrinology 1, 68–71 (2009)