Influence of low‐melting milk fat fraction on crystallization and physical properties of chocolate

B.Pajin1, I.Radujko1, Z.Šereš1, D.Šoronja Simović1, J.Gyura1, M.Sakač1
1Faculty of Technology, University of Novi Sad, Novi Sad, Serbia

Tóm tắt

PurposeInvestigated milk fat fraction differs in physical attributes, first of all in melting point and solid fat content and its influence on crystallization process of cocoa butter i.e. chocolate mass. It means that this fraction slows down crystallization rate, decreases melting point of mixture with cocoa butter and causes chocolate softness. It is very important for quality of chocolate especially chocolate with nuts or sunflower kernel. The aim of this paper was to investigate the influence of low‐melting (26°C) milk fat fraction on crystallization processes in chocolate mass and define the optimal concentration of this fraction with suitable precrystallization temperature time regime. Solid fat content of chocolate which designates the influence of precrystallization changes in chocolate mass with addition of milk fat fractions was investigated.Design/methodology/approachThe precrystallization was performed in a laboratory crystallizer that is in a modified Brabender pharinograph, which measures the rheological characteristics as indirect parameter of crystallization properties of chocolate mass depending on milk fat fraction concentration and precrystallization temperature. The experiments were performed according to the factorial plan 32(two factors on three levels) and the results are statistically treated.FindingsThe results showed that the optimal conditions for achieving the satisfactory tempering rate (optimal concentration of crystals in chocolate mass) are addition of 3 per cent low‐melting milk fat fraction and precrystallization temperature of 25°C.Originality/valueThe addition of high‐melting milk fat fraction slows down the chocolate mass crystallization more then low‐melting milk fat fraction. Investigated fraction influenced decreasing in solid fat content of chocolate regardless of precrystallization temperature.

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Tài liệu tham khảo

Afoakwa, E.O., Paterson, A. and Fowler, M. (2007), “Factors influencing rheological and textural qualities in chocolate – a review”, Trends in Food Science and Technology, Vol. 18, pp. 290‐8.

Attaie, H., Breitschuh, B., Braun, P. and Windhab, E.J. (2003), “The functionality of milk powder and its relationship to chocolate mass processing, in particular the effect of milk powder manufacturing and composition on the physical properties of chocolate masses”, International Journal of Food Science and Technology, Vol. 38, pp. 325‐35.

Beckett, S.T. (2008), Science of Chocolate, 2nd ed., RSC Publishing, Cambridge.

Chevalley, J. (1999), “Chocolate flow properties”, in Beckett, S.T. (Ed.), Industrial Chocolate Manufacture And Use, Chapman & Hall, New York, NY, pp. 182‐99.

Dimick, P.S., Reddy, S.Y. and Ziegler, G.R. (1996), “Chemical and thermal characteristics of milk‐fat fractions isolated by a melt crystallization”, Journal of the American Oil Chemists Society, Vol. 73 No. 12, pp. 1647‐52.

Hartel, R.W. (2001), Crystallization in Food, Aspen Publishers, Gaithersburg, MD.

Hartel, R.W. and Kaylegian, K.E. (2001), “Advances in milk fat fraction”, in Garti, N. and Sato, K. (Eds), Crystallization Processes in Fats and Lipids Systems, Marcel Dekker, New York, NY, pp. 381‐427, Chapter 11.

Hunter, S.R. (1960), “New reflectometer and its use for whiteness measurement”, Journal of the Optical Society of America, Vol. 50 No. 1, pp. 44‐8.

IOCCC (2000), Viscosity of Cocoa and Chocolate Products, Analytical Method 46, IOCCC (International Office of Cocoa, Chocolate and Sugar Confectionery Industries), available from CAOISCO, rue Defacqz 1, B‐1000 Bruxelles.

Jovanović, O. and Pajin, B. (2004), “Influence of lactic acid ester on chocolate quality”, Trends in Food Science and Technology, Vol. 15 Nos 1‐3, pp. 128‐36.

Kaylegian, K.E. and Lindsay, R.C. (1995) in Kaylegian, K.E. and Lindsay, R.C. (Eds), Handbook of Milkfat Fractionation Technology and Application, AOCS Press, Champaign, IL.

Leissner, R., Hogenbrik, G., Nilsson, J., Petersson, B., Alander, J., Helmbring, G., Stenmyr, C., Linghede, M. and Gunnerdal, J. (1997), Cocoa Butter Alternatives, Karlshamns Oils & Fats Academy, Karlshamn, pp. 102‐10.

Shukla, V.K.S., Goudappel, G.J., Gribnau, M.C.M. and van Doynhoven, J. (1999), “Solid fat content determination by NMR“”, INFORM, Vol. 10, pp. 479‐84.

Sonwaia, S. and Rousseaub, D. (2010), “Controlling fat bloom formation in chocolate – impact of milk fat on microstructure and fat phase crystallization”, Food Chemistry, Vol. 119 No. 1, pp. 286‐97.

Svenstrup, G., Heimdal, H. and Norgaard, L. (2005), “Rapid instrumental methods and chemometrics for the determination of pre‐crystallization in chocolate”, International Journal of Food Science and Technology, Vol. 40, pp. 953‐62.

Torbica, A., Jovanović, O. and Pajin, B. (2006), “The advantages of solid fat content determination in cocoa butter and cocoa butter equivalents by the Karlshamns method”, European Food Research and Technology, Vol. 222, pp. 385‐91.

Van Aken, G.A., ten Grotenhuis, E., van Langevelde, A.J. and Schenk, H. (1999), “Composition and crystallization of milk fat fraction”, Journal of the American Oil Chemists Society, Vol. 76, pp. 1323‐31.

Pajin, B. and Jovanović, O. (2004), “Influence of high‐melting milk fat fraction on quality and fat bloom stability of chocolate”, European Food Research and Technology, Vol. 220 Nos 3‐4, pp. 389‐95.