Influence of Nucleation Layers on MOVPE Growth of Semipolar ( $$11{\bar{2}}2$$ ) GaN on m-Plane Sapphire

Journal of Electronic Materials - Tập 50 - Trang 4533-4539 - 2021
A. Azizur Rahman1, Nirupam Hatui1, Carina B. Maliakkal1, Priti Gupta1, Jayesh B. Parmar1, Bhagyashree A. Chalke1, Arnab Bhattacharya1
1Department of Condensed Matter Physics and Material Science, Tata Institute of Fundamental Research, Mumbai, India

Tóm tắt

The influence of the underlying nucleation layer on the properties of semipolar $$(11{\bar{2}}2)$$ GaN grown on m-plane sapphire by metalorganic vapor-phase epitaxy has been investigated. $$(11{\bar{2}}2)$$ GaN epilayers of ~ 1 μm thickness were grown using four different initiating sequences: low-temperature AlN and GaN, and high-temperature AlN buffer layers, and directly (high-temperature GaN). The choice of nucleation layer had a pronounced effect on the surface morphology and crystal quality of the overlying GaN epilayer. In comparison, direct growth of $$(11{\bar{2}}2)$$ GaN without any buffer layer provided the best crystal quality with a rocking-curve $$\omega $$ full-width at half-maximum (FWHM) value of 720 arcsec along the $$[11{\bar{2}}{\bar{3}}]$$ direction and relatively enhanced near-band-edge photoluminescence emission, thus showing this direct growth process to be a simple route for synthesis of semipolar $$(11{\bar{2}}2)$$ GaN layers.

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