Improvement of the Electrical Properties of Cu-Poor CuInS2 Thin Films by Sodium Incorporation

Japanese Journal of Applied Physics - Tập 37 Số 11B - Trang L1370 - 1998
Takayuki Watanabe1, Hidenobu Nakazawa1, Masahiro Matsui1
1Central Laboratory, Asahi Chemical Industry Co., Ltd., 2-1 Samejima, Fuji, Shizuoka 416-0934, Japan

Tóm tắt

We investigated the effects of intentional sodium incorporation on the electrical conductivity of Cu-poor CuInS2 thin films. CuInS2 films were fabricated by sulfurization of In–S/Cu/Na2S/In precursors. Sodium incorporation resulted in a remarkable increase in the lateral conductivity and the cell efficiency of CuInS2-based solar cells. Photoluminescence measurements revealed that the enhancements were attributed to the annihilation of donor states, most likely In interstitials, by sodium incorporation.

Từ khóa


Tài liệu tham khảo

1995

1993, Adv. Mater., 5, 114, 10.1002/adma.19930050209

1996, Appl. Surf. Sci., 92, 232, 10.1016/0169-4332(95)00236-7

1994

1997, J. Appl. Phys., 81, 956, 10.1063/1.364224

1997, J. Appl. Phys., 81, 3667, 10.1063/1.365487

1997, Sol. Energy Mater. & Sol. Cells, 49, 423, 10.1016/S0927-0248(97)00127-X

1997, Sol. Energy Mater. & Sol. Cells, 49, 357, 10.1016/S0927-0248(97)00084-6

1996, Jpn. J. Appl. Phys., 35, 1681, 10.1143/JJAP.35.1681

1997, Jpn. J. Appl. Phys., 36, 732, 10.1143/JJAP.36.732

1994

1989, J. Phys. Chem. Solids, 50, 1297, 10.1016/0022-3697(89)90403-4

1965

1972

1934, Z. Krist., 87, 205

Jpn. J. Appl. Phys.