Identification of potent odourants in static headspace samples of green and black tea powders on the basis of aroma extract dilution analysis (AEDA)

Flavour and Fragrance Journal - Tập 8 Số 4 - Trang 173-178 - 1993
H. Guth1, Werner Grosch1
1Deutsche Forschungsanstalt für Lebensmittelchemie, Lichtenbergstasse, 4, D–8046 Garching, Germany

Tóm tắt

AbstractAroma extract dilution analysis (AEDA) of the volatile fractions of green and black tea samples revealed 28 odourants of which 27 were identified. As the odour quality and the chromatographic properties of most of the odourants occurring in the air above the tea powders agreed with those which were identified by the preceding AEDA, these compounds were detectable by gas chromatography–olfactometry (GC–O) in static headspace samples. (Z)‐Hex‐3‐enal, linalol, (Z)‐octa‐1,5‐dien‐3‐one, oct‐1‐en‐3‐one, (Z)‐hept‐4‐enal, butane‐2,3‐dione, 2‐methylpropanal, 3‐methylbutanal, 3‐methylnonane‐2,4‐dione, (E)‐non‐2‐enal, octanal, (E,Z)‐nona‐2,6‐dienal and hexanal were found in the headspace volume of 40 ml which was drawn at 40°C from both kinds of tea. (E, E)‐Nona‐2,4‐dienal and α‐pinene were detected as additional odourants of black tea. The most potent odourants occurring in the air above the tea powders were evaluated by the analysis of decreasing headspace volumes, e.g. (Z)‐hex‐3‐enal was the sole odourant in 2 ml of the headspace of green tea and linalol in 0.5 ml of that of black tea. This procedure indicated that the difference in the odours of green and black tea was mainly due to a higher concentration of (Z)‐hex‐3‐enal, (Z)‐octa‐1,5‐dien‐3‐one and butane‐2,3‐dione and the much lower concentration of linalol in the air above the former.

Từ khóa


Tài liệu tham khảo

Schaefer J., 1981, Handbuch der Aromaforschung, 37

10.1021/bk-1986-0317

Werkhoff P., 1989, Labor Praxis, 426

10.1021/jf60211a027

10.1007/BF01027663

10.1016/0924-2244(93)90187-F

10.1002/ffj.2730070408

10.1016/0308-8146(84)90082-7

10.1093/chromsci/4.11.395

10.1007/BF02542413

10.1007/BF01202626

Guth H., 1989, Fat Sci. Technol., 91, 225

10.1002/lipi.19680700102

10.1139/y59-099

10.1021/jf00004a028

Bemelmans J. H. M., 1979, Progress in Flavour Research, 79

Guth H., 1990, Lebensm. Wiss. Technol., 23, 59

Guth H., 1991, Food Sci. Technol., 93, 335

10.1002/hlca.19900730515

10.1002/jhrc.1240130507

10.1007/BF01192979

10.1271/bbb1961.39.243

10.1016/S0021-9673(01)85275-4

10.1002/hlca.19740570506

10.1021/jf60149a011

10.1271/bbb1961.27.193

10.1271/bbb1961.29.300

Goliya V. T., 1972, Prikl. Biokhem. Mikrobiol., 8, 600

1973, Chem. Abstr., 78, 40429p

Bokuchava M. A., 1957, Biokchimiya, 22, 561

1958, Chem. Abstr., 52, 2298f

10.1002/hlca.19740570126

10.1271/bbb1961.29.488

10.1016/S0021-9673(01)86393-7

10.1021/jf00104a035

10.1002/hlca.19660490609

Self R., 1963, Chem. Ind. (London), 863

10.1002/hlca.19670500610

10.1021/jf00124a055

Maarse H., 1989, Volatile Compounds in Food, 682

H.GuthandW.GroschinProgress in Flavor Precursor Studies ed. P. Schreier and P. Winterhalter in press.