Green sonochemical synthesis of silver nanoparticles at varying concentrations of κ-carrageenan

Nanoscale Research Letters - 2015
Randa Fawzi Elsupikhe1, Kamyar Shameli2, Mansor Bin Ahmad1, Nor Azowa Ibrahim1, Norhazlin Zainudin1
1Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia
2Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi Malaysia, Jalan Sultan Yahya Petra (Jalan Semarak), 54100, Kuala Lumpur, Malaysia

Tóm tắt

Abstract A green sonochemical method was developed for preparing silver nanoparticles (Ag-NPs) in different concentrations of kappa carrageenan (κ-carrageenan). The κ-carrageenan was used as a natural eco-friendly stabilizer, and ultrasonic irradiation was used as a green reducing agent. The number of Ag-NPs increased with increasing κ-carrageenan concentrations. Formation of Ag/κ-carrageenan was determined by UV-visible spectroscopy where the surface plasmon absorption maximum was observed at 402 to 420 nm. The X-ray diffraction (XRD) analysis showed that the Ag-NPs are of a face-centered cubic structure. The Fourier transform infrared (FT-IR) spectrum indicated the presence of Ag-NPs in κ-carrageenan. Transmission electron microscopy (TEM) image for the highest concentration of κ-carrageenan showed the distribution of Ag-NPs with an average particle size near to 4.21 nm. Scan electron microscopy (SEM) images illustrated the spherical shape of the Ag-NPs. The use of photo irradiation provides a green and economic feature to this work.

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