Formylation of porphyrin platinum complexes
Tóm tắt
The formylation reaction of platinum complexes of β-unsubstituted porphyrins was studied. The interaction of deuteroporphyrin IX derivatives with the Vilsmeyer reagent led to the selective formylation of their macrocycles in the β position. The resulting formyl derivatives of the porphyrins are of interest for fluorescent immunoassay.
Tài liệu tham khảo
Osin, N.S., Rumyantseva, V.D., Proshina, E.Yu., and Mironov, A.F., RF Patent 1707539, Byull. Izobret., 1992, no. 3.
Osin, N.S., Mironov, A.F., Rumyantseva, V.D., and Ponamoreva, O.N., RF Patent 2 066 455, Byull. Izobret., 1992, no. 25.
Papkovskii, D.B., Savitskii, A.P., Yaropolov, A.I., Ponomarev, G.V., Rumyantseva, V.D., and Mironov, A.F., Biomed. Sci., 1991, vol. 2, pp. 63–67.
Callot, H.J., Tetrahedron, 1973, vol. 29, pp. 899–901.
Buchler, J.W., Dreher, C., and Herget, G., Liebigs Ann. Chem., 1988, pp. 43–54.
Ponomarev, G.V., Yashunskii, D.V., and Moskovkin, A.S., Khim. Geterotsikl. Soedin., 1997, no. 3, pp. 324–328.
Vasil’ev, V.V., Borisov, S.M., Chubarova, Yu.O., and Rumyantseva, V.D., Zh. Neorg. Khim., 2003, vol. 48, pp. 455–461.
Brockmann, H., Bliesener, K.M., and Inhoffen, H.H., Liebigs Ann. Chem., 1968, vol. 718, pp. 148–161.
Mironov, A.F., Rumyantseva, V.D., Kulish, M.A., Kondukova, T.V., Rozynov, B.V., and Evstigneeva, R.P., Zh. Obshch. Khim., 1971, vol. 41, pp. 1114–1118.
Johnson, A.W. and Oldfield, D., J. Chem. Soc. (C), 1966, no. 8, pp. 794–798.
Rumyantseva, V.D., Aksenova, E.A., Ponamoreva, O.N., and Mironov, A.F., Bioorg. Khim., 2000, vol. 26, pp. 471–477.
Momenteau, M., Loock, B., and Bisagni, E., Can. J. Chem., 1979, vol. 57, pp. 1804–1813.
Ponomarev, G.V. and Maravin, G.B., Khim. Geterotsikl. Soedin., 1982, no. 1, pp. 59–64.
DiNello, R.K and Chang, C.K, in The Porphyrins, vol. 1, Dolphin, D., Ed., New York: Academic, 1978, pp. 294–296.
Lindsey, J.S., Schreiman, I.C., Hsu, H.C., Kearney, P.C., and Marguerettaz, A.M., J. Org. Chem., 1987, vol. 52, pp. 827–836.