Nobuko Kanehisa1, Yasushi Kai1, Nobutami Kasai1, Hajime Yasuda2, Yuushou Nakayama3, K. Takei3, Akira Nakamura3
1Department of Applied Chemistry, Faculty of Engineering, Osaka University
2Department of Applied Chemistry, Faculty of Engineering, Hiroshima University
3Department of Macromolecular Science, Faculty of Science, Osaka University
Tóm tắt
Abstract
Reactions of Group 4–6 metal halides with 2,6-dimethylphenoxy(trimethyl)silane in THF afford pure compounds of type MX1[O-2,6-(CH3)2C6H3]m(THF)n(M = Ti, Zr, Hf with l = 3, m = 1, n = 2 or l = 2, m = 2, n = 2; M = Nb, l = 4, m = 1, n = 1 or l = 3, m = 2, n = 1; M = W, l = 5, m = 1, n = 0 or l = 4, m = 2, n = 0) in >75% yields. Geometries of TiCl2[O-2,6-(CH3)2C6H3]2(THF)2 and NbCl3[O-2,6-(CH3)2C6H3]2(THF) were determined by the X-Ray diffraction method.
