Estimation of the surface free energy of polymers

Wiley - Tập 13 Số 8 - Trang 1741-1747 - 1969
D. K. Owens1, R. C. Wendt2
1E. I. du Pont de Nemours & Co., Spruance Film Research & Development Laboratory, Richmond, Virginia
2Yerkes Research Laboratory, Buffalo, New York

Tóm tắt

Abstract

A method for measuring the surface energy of solids and for resolving the surface energy into contributions from dispersion and dipole‐hydrogen bonding forces has been developed. It is based on the measurement of contact angles with water and methylene iodide. Good agreement has been obtained with the more laborious γc method. Evidence for a finite value of liquid‐solid interfacial tension at zero contact angle is presented. The method is especially applicable to the surface characterization of polymers.

Từ khóa


Tài liệu tham khảo

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