Effect of Solution Treatment on Precipitation Behaviors, Age Hardening Response and Creep Properties of Elektron21 Alloy Reinforced by AlN Nanoparticles

Materials - Tập 10 Số 12 - Trang 1380
Abdollah Saboori1, Elisa Padovano2, Matteo Pavese3, Hajo Dieringa4, Claudio Francesco Badini5
1Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy. [email protected].
2Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy. [email protected].
3Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy. [email protected].
4Helmholtz-Zentrum Geesthacht, Magnesium Innovation Centre-MagIC, Max-Planck Street 1, 21502 Geesthacht, Germany. [email protected].
5Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy. [email protected].

Tóm tắt

In the present study, the solution and ageing treatments behavior of Mg-RE-Zr-Zn alloy (Elektron21) and its nano-AlN reinforced nanocomposites have been evaluated. The properties of the thermal-treated materials were investigated in terms of Vickers hardness, the area fraction of precipitates, microstructure and phase composition. The solution treatments were performed by treating at 520 °C, 550 °C and 580 °C in argon atmosphere. The outcomes show that the hardness of the solutionized alloys was slightly affected by the solution temperature. X-ray diffraction and image analysis revealed that the complete dissolution of precipitates was not possible, neither for Elektron21 (El21) nor for its AlN containing nanocomposites. The ageing treatment of El21 led to a significant improvement in hardness after 20 h, while for longer times, it progressively decreased. The effect of ageing on the hardness of El21–AlN composites was found to be much less than this effect on the hardness of the host alloy. Electron backscatter diffraction (EBSD) analysis of El21 and El21–1%AlN after solution treatment confirm the random orientation of grains with a typical texture of random distribution. The as-cast creep results showed that the incorporation of nanoparticles could effectively improve the creep properties, while the results after solution treatment at 520 °C for 12 h followed by ageing treatment at 200 °C for 20 h confirmed that the minimum creep rate of T6-El21 was almost equal to the as-cast El21–AlN.

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Tài liệu tham khảo

Sillekens, 2014, The ExoMet Project: EU/ESA Research on high-performance light-metal alloys and nanocomposites, Metall. Mater. Trans. A, 45, 3349, 10.1007/s11661-014-2321-2

Mortensen, 2010, Metal Matrix Composites, Annu. Rev. Mater. Res., 40, 243, 10.1146/annurev-matsci-070909-104511

Saboori, 2017, Microstructure and thermal conductivity of Al-Graphene composites fabricated by powder metallurgy and hot rolling techniques, Acta Metall. Sin., 30, 675, 10.1007/s40195-017-0579-2

Saboori, 2017, Development of Al- and Cu-based nanocomposites reinforced by graphene nanoplatelets: Fabrication and characterization, Front. Mater. Sci., 11, 171, 10.1007/s11706-017-0377-9

Saboori, A., Pavese, M., Badini, C., and Fino, P. (2017). A Novel Cu—GNPs Nanocomposite with Improved Thermal and Mechanical Properties. Acta Metall. Sin., 1–5.

Hu, 2003, Potential magnesium alloys for high temperature die cast automotive applications: A Review, Mater. Manuf. Process., 18, 687, 10.1081/AMP-120024970

Kulekci, 2008, Magnesium and its alloys applications in automotive industry, Int. J. Adv. Manuf. Technol., 39, 851, 10.1007/s00170-007-1279-2

Lyon, 2007, Elektron 21—An aerospace magnesium alloy for sand cast and investment cast applications, Adv. Eng. Mater., 9, 793, 10.1002/adem.200700165

Musfirah, 2012, Magnesium and aluminum alloys in automotive industry, J. Appl. Sci. Res., 8, 4865

Polmear, 1994, Magnesium alloys and applications, Mater. Sci. Technol., 10, 1, 10.1179/mst.1994.10.1.1

Luo, 2013, Magnesium casting technology for structural applications, J. Magnes. Alloys, 1, 2, 10.1016/j.jma.2013.02.002

He, 2006, Precipitation in a Mg–10Gd–3Y–0.4Zr (wt.%) alloy during isothermal ageing at 250 °C, J. Alloys Compd., 421, 309, 10.1016/j.jallcom.2005.11.046

Moreno, 2003, Microstructural stability and creep of rare-earth containing magnesium alloys, Scr. Mater., 48, 1029, 10.1016/S1359-6462(02)00595-X

Czerwinski, F. (2011). Microstructure and properties of elektron 21 magnesium alloy. Magnesium Alloys—Design, Processing and Properties, InTech.

Negishi, 1995, Phase diagrams of magnesium-rich portion, aging characteristics and tensile properties of Mg-heavy rare earth metal (Gd, Dy)-Nd alloys, J. Jpn. Inst. Light Met., 45, 57, 10.2464/jilm.45.57

Yao, 1996, Precipitation and age-hardening in Al-Si-Cu-Mg-Fe casting alloys, Mater. Sci. Forum, 217–222, 777, 10.4028/www.scientific.net/MSF.217-222.777

Katsarou, 2016, Microstructure, mechanical properties and creep of magnesium alloy Elektron21 reinforced with AlN nanoparticles by ultrasound-assisted stirring, Mater. Sci. Eng. A, 659, 84, 10.1016/j.msea.2016.02.042

Saboori, A., Pavese, M., Badini, C., and Fino, P. (2017). A novel approach to enhance the mechanical strength and electrical and thermal conductivity of Cu-GNP nanocomposites. Metall. Mater. Trans. A.

Dieringa, 2011, Properties of magnesium alloys reinforced with nanoparticles and carbon nanotubes: A review, J. Mater. Sci., 46, 289, 10.1007/s10853-010-5010-6

Kielbus, 2010, DSC and microstructural investigations of the Elektron 21 magnesium alloy, Mater. Sci. Forum, 642, 1447, 10.4028/www.scientific.net/MSF.638-642.1447

Nie, 2000, Characterisation of strengthening precipitate phases in a Mg-Y-Nd alloy, Acta Mater., 48, 1691, 10.1016/S1359-6454(00)00013-6

Antion, 2003, Hardening precipitation in a Mg–4Y–3RE alloy, Acta Mater., 51, 5335, 10.1016/S1359-6454(03)00391-4

Shi, 2000, Wettability of molten magnesium on carbon and AlN, J. Jpn. Inst. Met. Mater., 64, 335, 10.2320/jinstmet1952.64.5_335

He, 1996, Reaction layer formation at the interface between Ti or Zr and AlN, Phys. Status Solidi A, 157, 99, 10.1002/pssa.2211570113

Arbey, 2013, Zirconium adsorption and incorporation on a reconstructed Al-T4 AlN(0001) surface, J. Phys. Chem. Solids, 74, 1387, 10.1016/j.jpcs.2013.04.019

Louis, 1994, A differential scanning calorimetry study of solid state reactions in AA6061-SiC, AA6061-Al2O3 and A357-SiC composites fabricated by means of compocasting, Mater. Sci. Eng. A, 189, 219, 10.1016/0921-5093(94)90418-9

Kouzeli, 2002, Size dependent strengthening in particle reinforced aluminium, Acta Mater., 50, 39, 10.1016/S1359-6454(01)00327-5

Kocks, 1966, A statistical theory of flow stress and work-hardening, Philos. Mag., 13, 541, 10.1080/14786436608212647

Arzt, 1988, The kinetics of dislocation climb over hard particles—II. Effects of an attractive particle-dislocation interaction, Acta Metall., 36, 1053, 10.1016/0001-6160(88)90159-9

Li, 1997, A simple procedure for estimating threshold stresses in the creep of metal matrix composites, Scr. Mater., 36, 1457, 10.1016/S1359-6462(97)00041-9