Differential thermal analysis of high polymers. II. Effects of diluents on melting behavior of polyethylenes

Wiley - Tập 50 Số 153 - Trang 79-86 - 1961
Bacon Kê1
1Research and Development Department, Standard Oil Company (Indiana), Whiting, Indiana

Tóm tắt

AbstractStudies of the nature and magnitude of the interaction between a polymer and a diluent are of both theoretical and practical importance. The effects of several liquid and solid diluents on the melting behavior of both high‐ and low‐density polyethylene have been studied by differential thermal analysis. The depression of melting point was related by a thermodynamic equation to the type and amount of the diluent. The thermodynamically derived true heat of fusion of polyethylene agrees well with the currently accepted value.

Từ khóa


Tài liệu tham khảo

10.1021/cr50011a001

Orthmann H. J., 1957, Z. Elecktrochem., 61, 106

10.1002/pol.1960.1204213903

10.1021/ie50575a035

Ke B., 1960, Organic Analysis

Flory J. P., 1953, Principles of Polymer Chemistry

Herz W., 1922, Z. physik. Chem., 101, 269

Auwers K. V., 1921, Ann., 422, 192

10.1016/0022-3697(58)90121-5

10.1021/ja01546a003

Block H., 1912, Z. physik. Chem., 78, 385

Delcourt Y., 1931, Bull. soc. chim. Belges, 40, 286, 10.1002/j.0037-9646.1931.tb00509.x

10.1063/1.1700567

10.1063/1.1722589