Determination of structural changes in microwaved rice starch using Fourier transform infrared and Raman spectroscopy

Starch/Staerke - Tập 64 Số 8 - Trang 598-606 - 2012
Daming Fan1, Wenrui Ma1, Liyun Wang1, Jianlian Huang2, Jianxin Zhao1, Hao Zhang1, Wei Chen1,3
1School of Food Science and Technology, Jiangnan University, Wuxi, P.R. China
2Fujian Anjoyfood Share Co. Ltd., Xiamen, P. R. China
3State Key Laboratory of Food Science and Technology, Jiangnan University, Wuxi, P.R. China

Tóm tắt

AbstractFTIR and confocal laser micro‐Raman spectroscopy methods were used to investigate the differences in chemical bond types, bond energy, and skeleton connection system between rice starch heated in a microwave and rice starch heated rapidly using a traditional method. The temperature of the peak absorption position of CH mode vibration of microwaved sample was lower and the temperature of peak position of CO related mode vibration on skeleton of microwaved sample were higher than those of the rapid heating sample, but there were no changes to other skeletal mode vibrations such as glycosidic linkage and pyranose ring. Overall, microwave‐heat treatment did not change the type of chemical groups in starch molecules, and induce the formation of new chemical group bonds, or change the way that they interact with each other in rice starch. Furthermore, the vibrational energy of the chemical‐bond of microwave‐treated rice starch changes gradually during the heating process.

Từ khóa


Tài liệu tham khảo

10.1039/cs9972600233

10.1080/10408690390251129

10.1002/star.200800147

10.1002/jsfa.2960

10.1021/jf011652p

10.1021/jf0102160

10.1016/S0144-8617(98)00010-1

10.1021/jf020643t

Xiong J., 2006, Influence of microwave irradiation on structures of tapioca starch, J. Chem. Ind. Eng. (China), 57, 1204

10.1016/S0308-8146(00)00130-8

10.3724/SP.J.1105.2008.00720

10.1016/S0924-2031(99)00080-6

Lu X., 2006, Decrease of residual protein in rice starch by neutral protease‐ultrasonic wave, Cereal Feed Ind., 11, 24

Li C. L., 2007, Study on the preparation of rice starch, Food Sci. Technol., 10, 68

10.1016/j.carbpol.2011.07.011

10.1002/star.19940461202

10.1111/j.1365-2621.1999.tb15104.x

10.1016/j.foodchem.2008.10.053

Long J. Y., 2002, A quantum chemistry research on electronic structure of starch molecules(1): Characteristics of basic structure unit, Indican bond and interior hydrogen bond, Guangxi Sci., 9, 34

10.1016/S0144-8617(97)00093-3

Yue W., 2010, Anti‐retrogradation of High‐amylose Rice Starch by Physical Modification and Detection and Characterization of Retrogradation

10.1016/S0924-2244(02)00243-1

Socrates G., 2004, Infrared and Raman Characteristic Group Frequencies: Tables and Charts

Jin Z. Y., 2008, Carbohydrate Chemistry – Theory and Application

10.1002/bip.1975.360140909

10.1007/BF03040801

10.1016/0008-6215(95)00412-2