Covalent organic frameworks comprising cobalt porphyrins for catalytic CO 2 reduction in water

American Association for the Advancement of Science (AAAS) - Tập 349 Số 6253 - Trang 1208-1213 - 2015
Song Lin1,2, Christian S. Diercks2,3, Yue‐Biao Zhang2,3,4, Nikolay Kornienko2, Eva M. Nichols1,2, Yingbo Zhao2, Aubrey R. Paris2, Dohyung Kim5, Peidong Yang2,5,6,3, Omar M. Yaghi2,6,7,3, Christopher J. Chang1,2,8,9
1Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
2Department of Chemistry, University of California, Berkeley, CA 94720 USA
3Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA.
4School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China
5Department of Materials Science and Engineering, University of California, Berkeley, CA 94720, USA.
6Kavli Energy Nanoscience Institute, Berkeley, CA 94720, USA
7King Fahd University of Petroleum and Minerals, Dhahran 34464, Saudi Arabia.
8Department of Molecular and Cell Biology, University of California, Berkeley, CA 94720, USA
9Howard Hughes Medical Institute, University of California, Berkeley, CA 94720, USA

Tóm tắt

Improving cobalt catalysts Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin et al. now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF. The resulting material showed greatly enhanced activity for the aqueous electrochemical reduction of CO 2 to CO. Science , this issue p. 1208

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