Chiral and Achiral Crystal Structures

Helvetica Chimica Acta - Tập 86 Số 4 - Trang 905-921 - 2003
H. D. Flack1
1Laboratoire de Cristallographie, University of Geneva, 24 quai Ernest-Ansermet, CH1211 Geneva 4 (phone: + 41 22 702 62 49, fax: + 41 22 702 61 08)

Tóm tắt

Abstract

An extensive study and analysis of the concepts, classification, presentation, and nomenclature of chirality and lack of chirality in crystal structures and their constituents is presented. Oriented crystal structures are classified. The chirality rules for existence of molecular crystal structures are examined and the relation to segmentation and latent symmetry highlighted. The nomenclature of chirality and related terms, and the relationship of chirality to optical activity is covered. The uses and limitations of the Euclidean normalizer are treated. An improved glossary of terms is included.

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Tài liệu tham khảo

E. Koch W. Fischer U. Müller

10.1021/cr970096o

L. D. Barron

L. D. Barron

10.1107/S0108767399004262

10.1107/S0021889800007184

10.1107/S0108767386099890

10.1107/S0108767383001762

10.1107/S0108767385001064

10.1107/S0108767387099859

10.1107/S0108767388002697

J. Jacques A. Collet S. H. Wilen

10.1107/S0108768100002172

10.1021/ja00344a003

H.‐B. Bürgi (Department of Chemistry and Biochemistry) personal communication 2000.

10.1107/S0108767301004676

10.1107/S0108767301016725

10.1039/ct8977100989

10.1039/CT8987300606

10.1039/ct8997501119

10.1021/ja00026a015

10.1002/jlac.18952860105

10.1351/pac199668122193

Francotte E., 1996, Chimie Nouvelle, 14, 1541

Francotte E., 1997, Chimia, 51, 717, 10.2533/chimia.1997.717

10.1016/S0378-4347(96)00242-3

Roozeboom H. W. B., 1899, Z. Phys. Chem., 28, 494, 10.1515/zpch-1899-2832

Coquerel G., 2000, Enantiomer, 5, 481

W. H. Thomson

10.1107/S0108768102003890

H. A. Hauptman ‘Crystal Structure Determination’ Plenum New York 1972.

D. Rogers

10.1107/S0108767386099749

10.1107/S0108767388011067

10.1107/S0108767393005860

10.1107/S0108767394013656

10.1107/S0108767394013644

T. Hahn H. Klapper

L. D. Barron

10.1088/0034-4885/63/10/201

10.1143/JPSJ.17.725

10.1021/cr60323a003

10.1080/01411590108224558

A. Lingard Ph. D. Thesis University of Oxford 1994.

10.1107/S0567739469001410

10.1107/S0108768191011746

10.1107/S0567739468001440

10.1016/0030-4018(74)90244-2

10.1107/S0021889899014168

10.1038/180513b0

10.1038/182198a0

10.1107/S0108767388011055

10.1126/science.935852

H. Wondratschek

L Sohncke

J. J. Burckhardt

Wolff de, 1992, Acta Crystallogr., Sect. A, 4

10.1107/S0108767389002230

Flack H. D., 2000, Acta Crystallogr., Sect. A, 5

10.1107/S0108767398018418

Y. Billiet E. F. Bertaut

10.1021/cm00044a010