Yin Hu1, Wei Chen1, Tianyu Lei1, Bin Zhou2, Yu Jiao3, Yichao Yan1, Xinchuan Du1, Jianwen Huang1, Chunyang Wu1, Xuepeng Wang1, Yang Wang1, Bo Chen4, Jun Xu5, Chao Wang1, Jie Xiong1
1State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054, China
2Aviation Engineering College Civil Flight University of China Guanghan 618307 China
3School of Applied and Chemical Engineering Xichang College Xichang 615053 China
4Institute of Microelectronics of Chinese Academy of Sciences, Beijing 100029, China
5School of Electronic Science & Applied Physics Hefei University of Technology Hefei 230009 China
Tóm tắt
AbstractSignificant progress has achieved for developing lithium–sulfur (Li–S) batteries with high specific capacities and excellent cyclic stability. However, some critical issues emerge when attempts are made to raise the areal sulfur loading and increase the operation current density to meet the standards for various industrial applications. In this work, polyethylenimine‐functionalized carbon dots (PEI‐CDots) are designed and prepared for enhancing performance of the Li–S batteries with high sulfur loadings and operation under high current density situations. Strong chemical binding effects towards polysulfides and fast ion transport property are achieved in the PEI‐CDots‐modified cathodes. At a high current density of 8 mA cm−2, the PEI‐CDots‐modified Li–S battery delivers a reversible areal capacity of 3.3 mAh cm−2 with only 0.07% capacity decay per cycle over 400 cycles at 6.6 mg sulfur loading. Detailed analysis, involving electrochemical impedance spectroscopy, cyclic voltammetry, and density functional theory calculations, is done for the elucidation of the underlying enhancement mechanism by the PEI‐CDots. The strongly localized sulfur species and the promoted Li+ ion conductivity at the cathode–electrolyte interface are revealed to enable high‐performance Li–S batteries with high sulfur loading and large operational current.
