Biogenous ethers: production and operation in a diesel engine

Aleksandar Damyanov1, Peter Hofmann1, Bernhard Geringer1, Nikolaus Schwaiger2, Thomas Pichler2, Matthäus Siebenhofer2
1Institute for Powertrains and Automotive Technology, Vienna University of Technology, Vienna, Austria
2Institute of Chemical Engineering and Environmental Technology, Graz University of Technology, Graz, Austria

Tóm tắt

Từ khóa


Tài liệu tham khảo

Eurostat: Greenhouse gas emission statistics—emission inventories (2017) Online article. http://ec.europa.eu/eurostat/statistics-explained/index.php/Greenhouse_gas_emission_statistics . Accessed 13 June 2017

Schwaiger, N.: Lignozellulose basierte sauerstoffhaltige Dieselersatzkraftstoffe; Study; Technische Universität Graz, Institut für chemische Verfahrenstechnik und Umwelttechnik; März 2015, Graz, Austria (2015)

Pischinger, S., Hoppe, F., Krieck, M., Budak, O., Zubel, M., Graziano, B., Heuser, B., Kremer, F.: Fuel design for future combustion engines—a view from the cluster “Tailor-Made Fuels from Biomass”; Lenz (Hrsg.); ISBN 978-3-18-379912-1; 37. Internationales Wiener Motorensymposium, 28–29 April 2016, Vienna (2016)

Janssen, A., Kremer, F., Baron, H., Muether, M., Pischinger, S., Klankermayer, J.: Tailor-made fuels from biomass for homogeneous low-temperature diesel combustion. Energy Fuels 25, 4734–4744 (2011). https://doi.org/10.1021/ef2010139

Graziano, B., Jakob, M., Kremer, F., Pischinger, S., Lee, C., Fernandes, R.: Investigation on the ignition sensitivity of 2-MTHF, heptane and di-n-butylether. In: Proceedings of the 6th European Combustion Meeting; 25th to 28th of June, 2013; Lund, University, Sweden (2013)

Kremer, F., Heuser, B., Pischinger, S., Klankermayer, J.: Optimizing diesel combustion behaviour with tailor-made fuels from biomass. In: Proceedings of the 9th International Colloquium Fuels 15th to 17th of January 2013, Ostfildern (2013)

Janssen, A., Jakob, M., Muether, Pischinger, S., Klankermayer, J.: Tailor-made fuels from biomass for partly homogenous low temperature combustion systems. In: Proceedings of the 20th Aachen Colloquium Automobile and Engine Technology, Aachen (2011)

Pischinger, S., Kremer, F., Hoppe, F., Heuser, B.: Fuel as a design parameter for future low emission engines. In: JSAE/SAE Powertrains, Fuels & Lubricants Meeting, Conference, Kyoto Japan, September (2015)

Heuser, B., Jakob, M., Kremer, F., Pischinger, S., Kerschgens, B., Pitsch, H.: Tailor-made fuels from biomass: influence of molecular structures on the exhaust gas emissions of compression ignition engines (No. 2013-36-0571). SAE Technical Paper (2013)

Boot, M.: Biofuels from Lignocellulosic Biomass. Innovations beyond Bioethanol. Wiley-VCH Verlag GmbH & Co. (2016) (ISBN: 978-3-527-33813-9)

Beeckmann, J., Aye, M., Gehmlich, R., Peters, N.: Experimental investigation of the spray characteristics of dI-n-butyl ether (DNBE) as an oxygenated compound in diesel fuel; SAE paper 2010-01-1502; ISSN 0148–7191; https://doi.org/10.4271/2010-01-1502

Härtl, M., Gaukel, K., Pelerin, D., Wachtmeister, G.: Oxymethylenether als potenziell CO2-neutraler Kraftstoff für saubere Dieselmotoren. Teil 1: MotoruntersuchungenMTZ Motortechnische Zeitschrift 02/2017, 78. Jahrgang, p. 52–58

Gaukel, K., Pelerin, D., Härtl, M., Wachtmeister, G., Burger, J., Maus, W., Jacob, E.: The fuel OME2: an example to pave the way to emission-neutral vehicles with internal combustion enginelenz (Hrsg.) ISBN 978-3-18-379912-137. Internationales Wiener Motorensymposium, 28–29 April 2016, Vienna (2016)

Härtl, M., Seidenspinner, P., Jacob, E., Wachtmeister, G.: Oxygenate screening on a heavy-duty diesel engine and emission characteristics of highly oxygenated oxymethylene ether fuel OME1. Fuel J. 153 328–335 (2015). https://doi.org/10.1016/j.fuel.2015.03.012

Pellegrini, L., Marchionna, M., Patrini, R., Beatrice, C., Del Giacomo, N., Guido, C.: Combustion behaviour and emission performance of neat and blended polyoxymethylene dimethyl ethers in a light-duty diesel engine SAE 2012-01-1053

Lumpp, B., Rothe, D., Pastötter, C., Lämmermann, R., Jacob, E.: Oxymethylenether als Dieselkraftstoffzusätze der Zukunft MTZ Motortechnische Zeitschrift 03/2011, 72. Jahrgang, pp. 198–202

Härtl, M., Seidenspinner, P., Wachtmeister, G., Jacob, E.: Synthetischer Dieselkraftstoff OME1—Lösungsansatz für den Zielkonflikt NOx-/Partikel-Emission MTZ Motortechnische Zeitschrift 07-08/2014, 75. Jahrgang, pp. 68–73

Feiling, A., Münz, M., Beidl, C.: Potential of the synthetic fuel OME1b for the soot-free diesel Engine MTZextra; fuels and lubricants of the future, pp. 16–21 (2016)

Richter, G., Zellbeck, H.: OME als Kraftstoffersatz im Pkw-Dieselmotor; MTZ Motortechnische Zeitschrift 12/2017, 78. Jahrgang, pp. 66–72

Damyanov, A., Hofmann, P., Drack, J., Pichler, T., Schwaiger, N., Siebenhofer, M.: Operation of a diesel engine with biogenous oxymethylene ethers. In: Proceedings of the 26th Aachen Colloquium Automobile and Technology, pp. 289–314 (2017)

Richtlinie: 2009/28/EG des Europäischen Parlaments und des Rates vom 23. April 2009 zur Förderung der Nutzung von Energie aus erneuerbaren Quellen und zur Änderung und anschließenden Aufhebung der Richtlinien 2001/77/EG und 2003/30/EG.Amtsblatt der Europäischen Union L 140/16, 5.6.2009 (2009)

Crusius, S., Müller, M., Stein, H.: Oxy-methylen-di-methylether (OMDME or OMEx) as an alternative for diesel fuel: properties, additivation and first engine tests nikolai schubert (Hrsg.). In: Proceedings of the 11th International Colloquium Fuels; Ostfildern, June 27–29, (2017)

Damyanov, A., Hofmann, P., Derntl, M., Schüßler, M., Pichler, T., Schwaiger, N., Siebenhofer, M.: Regenerative oxygen-containing diesel substitute fuels as an ecological option for increasing efficiency and minimizing emissions; nikolai schubert (Hrsg.). In: Proceedings of the 11th International Colloquium Fuels; Ostfildern, June 27–29, (2017)

Humbird, D., Davis, R., Tao, L., Kinchin, C., Hsu, D., Aden, A.: Process design and economics for biochemical conversion of lignocellulosic biomass to ethanol. Renew. Energy 303, 147 (2011)

Alriols, M.G., García, a, Llano-ponte, R., Labidi, J.: Combined organosolv and ultrafiltration lignocellulosic biorefinery process. Chem. Eng. J. 157(1), 113–120 (2010)

BioGrace—harmonised calculations of biofuel greenhouse gas emissions in Europe. [Online] (2015). http://www.biograce.net/ . Accessed 13 Apr 2015

Pichler, T.: Simulation und bewertung der herstellung von sauerstoffhaltigen dieselersatzkraftstoffen aus zellulose und hemizellulose”, Diplomarbeit, Graz University of Technology, (2016)

Berteau, P., Delmon, B.: Modified aluminas: relationship between activity in 1-butanol dehydration and acidity measured by NH3 TPD. Catalysis Today 5, 121–137 (1989)

Ströfer, E., Hasse, H., Schelling, H., Blagov, S.: Method for the production of polyoxymethylene dialkyl ethers from trioxan and dialkylethers. Patent (US7999140); 12.06.2006 (2006)  

Schelling, H., Ströfer, E., Pinkos, R., Haunert, A., Tebben, G.D., Hasse, H., Blagov, S.: Method for producing polyoxymethylene dimethyl ethers. Patent (WO 2006045506); 19.10.2005 (2005)  

Ströfer, E., Sinnen, R., Schweers, O., Thiel, J., Hasse, H., Siegert, M.: Fuel mixture comprising polyoxymethylene dialkyl ether. Patent (WO 2008074704); 12.12.2007 (2007)

Tebben, G.D., Schelling, H., Ströfer, E., Pinkos, R., Haunert, A., Eiermann, M., Karl, J.: Biodiesel fuel mixture containing polyoxymethylene dialkyl ether. Patent (WO 2007000428); 26.06.2006 (2006)  

Burger, J., Hasse, H.: Multi-objective optimization using reduced models in conceptual design of a fuel additive production process. Chem. Eng. Sci. 99, 118–126 (2013)

Burger, J., Ströfer, E., Hasse, H.: Production process for diesel fuel components poly(oxymethylene) dimethyl ethers from methane-based products by hierarchical optimization with varying model depth. Chem. Eng. Res. Design 91, 2648–2662. https://doi.org/10.1016/j.ces.2013.05.049 (2013)

Schmitz, N., Burger, J., Ströfer, E., Hasse, H.: From methanol to the oxygenated diesel fuel poly(oxymethylene)dimethyl ether: an assessment of the production costs. Fuel J. 185, 67–72 https://doi.org/10.1016/j.fuel.2016.07.085 (2016)

Sauer, J., Arnold, U., Dahmen, N.: Synthetic fuels from biomass: potentials and viability. Springer Fachmedien Wiesbaden 2016. J. Liebl, C., Beidl (Hrsg.); https://doi.org/10.1007/978-3-658-12918-7_34 . Internationaler Motorenkongress (2016)

Arnold, U., Lautenschütz, L., Haltenort, P., Niethammer, B., Oestreich, D., Sauer, J.: Alternative diesel fuels: Feedstocks, production and potentials; Nikolai Schubert (Hrsg.). In: 11th International Colloquium Fuels; Ostfildern, June 27–29 (2017)

Kaltschmitt, M., Hartmann, H., Hofbauer, H.: Energie aus biomasse. Springer, Berlin, Heidelberg. ISBN 978-3-540-85095-3 (2009)

Petersen, S.: Carbo-V® biomass gasification technology: status after application of sound engineering practices (2015)

Linde, A.G.: Engineering Division, Dr.-Carl-von-Linde-Strasse 6–14, 82049 Pullach G Discover the Carbo-V® process

UOP Selexol™ Technology for Acid Gas Removal; UOP 5241; https://www.uop.com/?document=uop-selexol-technology-for-acid-gas-removal&download=1 (2009)

Air products liquid phase conversion company Commercial-scale demonstration of the liquid phase methanol (LPMEOH) process, (2004)

Reuss, G., Disteldorf, W., Gamer, A.O., Hilt, A.: Formaldehyde. https://doi.org/10.1002/14356007.a11_619 Ulmann’s Encycl. pp. 735–768, (2000)

Grützner, T., Lang, N., Siegert, M., Ströfer, E., Hasse, H.: Development of a new distillation based process for trioxane production. Institution of chemical engineers. ISBN 0-85295-505-7 Institution of chemical engineers symposium series, vol. 152; p. 336–343; Distillation and absorption 2006, Distillation and Absorption Conference, p. 8 (2006)

Liu, H., Gao, H., Ma, Y., et al.: Synthesis of high-purity methylal via extractive catalytic distillation. Chem. Eng. Technol. 35, 841–846 (2012). https://doi.org/10.1002/ceat.201100446

Pickett, L., Siebers, D., Idicheria, C.: Relationship between ignition processes and the lift-off length of diesel fuel jets; SAE paper 2005-01-3843; ISSN 0148–7191; https://doi.org/10.4271/2005-01-3843

Drack, J.: Bewertung der Herstellung von sauerstoffhaltigen Dieselersatzkraftstoffen durch indirekte Biomasseverflüssigung, Diplomarbeit, Graz University of Technology (2015)

Ulrich, G.D., Vasudevan, P.T.: Chemical engineering process design and economics: a practical guide. Process Publishing. ISBN 0970876823, 9780970876829 (2004)

Zhu, Y., Hinds, W.C., Kim, S., Sioutas, C.: Concentration and size distribution of ultrafine particles near a major highway. J. Air Waste Manag. Assoc. 52, 1032–1042 (2002)

Pelerin, D., Gaukel, K., Härtl, M., Wachtmeister, G.: Simplifying of the fuel injection system and lowest emissions with the alternative diesel fuel oxymethylene ether. In: Proceedings of the 16th Conference “The Working Process of the Internal Combustion Engine”, September 28–29, 2017; Graz (2017)