Axial Preference of Methylthio Substituent in Dioxaphosphorinanyl Ring System

Andrzej Okruszek1, Wojciech J. Stec1
1Polish Academy of Sciences, Centre of Molecular and Macromolecular Studies, 90-362 Łodź, Boczna 5, Poland

Tóm tắt

The spatial disposition of a 2-methylthio group in the 4-methyl-1,3,2-dioxaphosphorinanyl ring system was studied by stereochemical correlation, 1H, 13C and 81P NM-R. It has been established that a CH3S-group prefers an axial orientation much more strongly than does a methoxy group.

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