Argillation of Three Silicate Rocks Expressed in Terms of Ion Transfer

Walter Keller1
1University of Missouri and University of Arizona, USA

Tóm tắt

AbstractThe transfer of ions during the weathering of a Medford diabase, a granite from British Guiana, and of the Cheto Arizona tuff is traced by recasting the analyses of the fresh rocks and their altered counterparts into 160-oxygen rock cells, and by comparing algebraically the products of the weathering reaction with the original reactants.Hydrolysis and hydration are the first steps in the reaction. H ions were added in the weathering environment of the diabase and granite, but Mg ions were added in the change of tuff to bentonite.Silica and alkali metal ions are dissolved and removed during weathering of the diabase and granite, presumably under acid conditions, but it appears that the Cheto tuff was formed under a non-acid environment where Mg was added. During the hydrolysis of silicate rocks, H ions are concentrated temporarily in the clay minerals on land, while OH ions go to the ocean.More examples of ion transfer during weathering than the three given herein are needed to define the reactions occurring in the many environments of alteration which rocks encounter.

Từ khóa


Tài liệu tham khảo

Nutting, 1943a, Adsorbent clays: Their distribution, properties, production, and uses, U.S. Geol. Sur. Bull., 928, 127

Millot, 1949, Relations entre la constitution et la genèse des roches sèdi- mentaires argileuses, 352

Nutting, 1943b, The action of some aqueous solutions on clays of the montmo- rillonite group, U.S. Geol. Sur. Prof. Paper, 217

10.2475/ajs.250.8.594

Harrison, 1933, The katamorphism of igneous rocks under humid tropical conditions

10.1111/j.1151-2916.1935.tb19394.x

10.1086/624619

10.2113/gsecongeo.50.5.469

10.1130/0016-7606(1951)62[221:MOW]2.0.CO;2

Frederickson, 1954, Solubility” of albite in hydrothermal solutions, Am. Mineral., 39, 738

Ross, 1943, Clays and soils in relation to geologic processes, Jour. Wash. Acad. Sci., 33, 225

Leith, 1915, Metamorphic geology, 337

Keller, 1955, The principles of chemical weathering, 88

Haseman, 1945, The use of heavy minerals in studies of the origin and development of soils, Univ. Mo. Agr. Exp. Sta. Research Bull., 387, 75

10.1086/625477

Keller, 1952, Analcime in the Popo Agie member of the Chugwater formation, 70

10.2475/ajs.252.2.87