Alcaloïde des Canneberges du Nouveau-Brunswick

Experientia - Tập 27 - Trang 1141-1143 - 1971
K. Jankowski1, Janice Boudreau1, Iowna Jankowska1
1Département de Chimie, Université de Moncton, Moncton, Canada

Tóm tắt

A new alkaloid C20H22O2N2 (cannagunine) obtained from canadian Vaccinium Oxycoccus is shown to have structure 1. The structure of this compound was supported by NMR-, SM-, IR- and UV-spectra.

Tài liệu tham khảo

L. D. Antonaccio, N. A. Pereira, B. Gilbert, H. Vorbrueggen, H. Budzikiewicz, J. M. Wilson, L.J. Durham andC. Djerassi, J. Am. chem. Soc.84, 2161 (1962). G. Spiteller etM. Spiteller-Friedmann, Mh. Chem.93, 795 (1962). H. Budzikiewicz, D. H. Williams etC. Djerassi,Structure Elucidation of Natural Products by Mass Spectrometry (Holden-Day, Inc., San Francisco 1964), Vol. 1, p. 77. J. Lederberg,Computation of Molecular Formules for Mass Spectrometry (Holden-Day, San Francisco 1964). R. M. Silverstein etG. C. Bassler,Spectrometric Identification of Organic Compounds (J. Wiley et Sons, Inc., New York 1967), p. 168. R. M. Silverstein etG. C. Bassler,Spectrometric Identification of Organic Compounds (J. Wiley et Sons, Inc., New York 1967), p. 140. L. Friedman etF. A. Long, J. Am. chem. Soc.75, 2832 (1953). K. Jankowski, Can. J. Chem., in press (1971).